CO₂ is the primary contributor to global warming, and also the most significant anthropogenic emission gas in cities. This study investigates near-surface CO₂ spatiotemporal variability patterns at the community scale to address the critical gap in urban CO₂ high-resolution measurement and promote urban carbon neutrality. Combining fixed and mobile monitoring across five representative communities (1-km² coverage) with two-hour temporal precision and 20 m spatial resolution, results revealed average CO₂ concentrations of 440–480 ppm, exhibiting bimodal diurnal cycles and highlighting spatiotemporal divergent emission behaviors. Three communities peaked during 17:00–19:00 LT, while two peaked during 08:00–10:00 LT. Spatial correlation analysis identified two dominant patterns: road-adjacent “externally dominated” hotspots and “internally dominated” zones with elevated intra-community levels. Spearman correlation analysis, Random Forest, and Geographically and Temporally Weighted Regression models quantified spatial morphology and element contributions, demonstrating that building morphology exerted time-varying impacts across communities. Meanwhile, external traffic contributed 18–39% to concentration variability, while internal traffic and energy consumption drove localized peaks. The findings indicated that apart from the emission sources, the micro-scale urban spatial design elements also regulate the near-surface CO₂ distribution. This high-resolution approach provides actionable insights for optimizing community layouts and infrastructure to mitigate localized emissions, advancing carbon neutrality targeted urban planning.