TiNb₂O₇ has been considered as a promising anode material for next-generation high power lithium ion batteries for its relatively high theoretical capacity, excellent safety and long cycle life. However, the unsatisfactory electrochemical kinetics resulting from the intrinsic sluggish electron transport and lithium ion diffusion of TiNb₂O₇ limit its wide application. Morphology controlling and carbon coating are two effective methods for improving the electrochemical performance of electrode materials. Herein, an ultrathin carbon-coated porous TiNb₂O₇ nanosheet (TNO@C) is successfully fabricated by a simple and effective approach. The distinctive sheet-like porous structure can shorten the transport path of ions/electrons and provide more active sites for electrochemical reaction. The introduction of nanolayer carbon can improve electronic conductivity and increase the specific surface area of the porous TiNb₂O₇ nanosheets. Based on the above synergistic effect, TiNb₂O₇@C delivers an initial discharge capacity of 250.6 mAh g⁻¹ under current density of 5C and can be maintained at 206.9 mAh g⁻¹ after 1000 cycles with a capacity retention of 82.6%, both of which are superior to that of pure TiNb₂O₇. These results well demonstrate that TiNb₂O₇@C is a promising anode material for lithium ion batteries.

Plasmon-induced photocatalysis on noble metal surfaces has attracted broad attention due to its application in sunlight energy conversion, while the selectivity of plasmonic platforms remains unclear. Herein, we present the controlled plasmon-mediated oxidation of para-aminothiophenol (p-ATP) by employing Au@Ag core–shell nanostars with tunable tip plasmons in visible–near-infrared range as reactors. In-situ Raman measurements indicate that Au@Ag core–shell nanostars essentially promote the conversion of p-ATP to 4,4′-dimercaptoazobenzene (DMAB) due to hot carriers excited by localized surface plasmon resonance. Au@Ag nanostars with plasmon modes under resonant light excitation suggested higher catalytic efficiency, as evidenced by the larger intensity ratios between 1440 cm⁻¹ (N=N stretching of DMAB) and 1080 cm⁻¹ shifts (C–S stretching of p-ATP). Importantly, the time-dependent surface-enhanced Raman scattering spectra showed that the conversion efficiency of p-ATP was mainly dictated by the resonance condition between the tip plasmon mode of Au@Ag core–shell nanostars and the excitation light, as well as the choice of excitation wavelength. These results show that plasmon bands of metal nanostructures play an important role in the efficiency of plasmon-driven photocatalysis.

Lithium sulfide (Li₂S) is considered to be the best potential substitution for sulfur-based cathodes due to its high theoretical specific capacity (1166 mAh g⁻¹) and good compatibility with lithium metal-free anodes. However, the electrical insulation nature of Li₂S and severe shuttling of lithium polysulfides lead to poor rate capability and cycling stability. Confining Li₂S into polar conductive porous carbon is regarded as a promising strategy to solve these problems. In this work, N-doped porous carbon microspheres (NPCMs) derived from yeasts are designed and synthesized as a host to confine Li₂S. Nano Li₂S is successfully entered into the NPCMs’ pores to form N-doped porous carbon microspheres–Li₂S composite (NPCMs–Li₂S) by a typical liquid infiltration–evaporation method. NPCMs–Li₂S not only delivers a high initial discharge capacity of 1077 mAh g⁻¹ at 0.2 A g⁻¹, but also displays good rate capability of 198 mAh g⁻¹ at 5.0 A g⁻¹ and long-term lifespan over 500 cycles. The improved cycling and high-rate performance of NPCMs–Li₂S can be attributed to the NPCMs’ host, realizing the strong fixation of LiPSs and enhancing the electron and charge conduction of Li₂S in NPCMs–Li₂S cathodes.

Vacuum insulation panels (VIPs) have emerged as a cutting-edge strategy for achieving superior thermal insulation across a wide range of applications, including refrigerators, cold-chain transportation and building envelopes. The key factor for the exceptional performance of VIPs is maintaining an ultralow pressure environment within the panels, which is crucial for minimizing heat transfer. However, the presence of non-condensable gases can compromise the vacuum state, leading to a reduced insulation effectiveness during a panel’s service life. This review offers a comprehensive analysis of getter materials used in VIPs, focusing on their fundamental properties, types, integration techniques and performance characteristics, further emphasizing the challenges and potential directions for the development of getter materials. Overall, this review intends to provide novel insights into the development of getter materials for use in VIPs, offering essential viewpoints to aid future studies on this topic.