In natural materials, thermal expansion is typically positive, and negative thermal expansion is rarely observed. The tunable thermal expansion properties of mechanical metamaterials offer a promising solution to challenges caused by rapid temperature fluctuations. Therefore, this study proposes a dual-material double-trapezoidal hexagonal mechanical metamaterial (DTH), and derives the thermoelastic equations that build the relationship between temperature, external force, and displacement. Through theoretical analysis and numerical simulation, the intrinsic mechanism between the CTE and geometric parameters of DTH is revealed. Through the synergistic effect of dual materials and structural design, this metamaterial not only achieves thermal expansion regulation but also enhanced lightweight performance. The results show that by controlling the geometric parameters of DTH, the adjustment of effective CTE and elastic modulus can be realized, and the metamaterial composed of positive CTE materials can achieve a range of thermal expansion behaviors, including near-zero CTE and negative CTE. The tunable thermal expansion range extends from +39.92 ppm/°C to −3640.6191 ppm/°C. The metamaterials proposed in this study are not only superior to traditional materials in terms of thermal expansion performance but also have the characteristics of light weight and simple structure. This multifunctional material achieves higher performance and adaptability in applications.