Access to reliable low-voltage power is challenging where distribution networks are unavailable or uneconomic, including switching substations, construction sites, and remote communities. Station Service Voltage Transformers (SSVTs), also known as Power Voltage Transformers (PVTs), address this problem by supplying useful low-voltage power from transmission or subtransmission networks. This paper reviews SSVT terminology, operating principles, construction architectures, electromagnetic and thermal modeling, testing, reliability, monitoring, and applications. The most extensively documented applications concern substation auxiliary services, while rural minisubstations are supported by SSVT-specific development studies and selected field reports. Electric mobility has progressed beyond a prospective concept: an SSVT-based, transmission-connected micro-substation pilot has demonstrated direct 220 kV-to-low-voltage supply for electric-vehicle (EV) charging. However, SSVT-specific characterization for this application, long-term operating data, and application-oriented design guidance remain limited. Key research gaps concern coupled multiphysics validation, nonlinear-load performance, reliability statistics, techno-economic assessment, and life-cycle analysis. Particular attention is given to distinguishing applications already demonstrated with SSVT technology from emerging uses for which validation, standardization, or long-term operating experience remains limited. The review concludes by proposing a roadmap to develop reproducible, experimentally validated, and digitally supported SSVT platforms for remote energy access and selected electric-mobility applications.