Remotely operated vehicles (ROVs) face challenges in achieving optimal trajectory tracking performance during underwater movement due to external disturbances and parameter uncertainties. To address this issue, this paper proposes a position and attitude control strategy for underwater robots based on a reinforcement learning active disturbance rejection controller. The linear active disturbance rejection controller has achieved satisfactory results in the field of underwater robot control. However, fixed-parameter controllers cannot achieve optimal control performance for the controlled object. Therefore, further exploration of the adaptive capability of control parameters based on the linear active disturbance rejection controller was conducted. The deep deterministic policy gradient (DDPG) algorithm was used to optimize the linear extended state observer (LESO). This strategy employs deep neural networks to adjust the LESO parameters online based on measured states, allowing for more accurate estimation of model uncertainties and environmental disturbances, and compensating the total disturbance into the control input online, resulting in better disturbance estimation and control performance. Simulation results show that the proposed control scheme, compared to PID and fixed parameter LADRC, as well as the double closed-loop sliding mode control method based on nonlinear observers (NESO-DSMC), significantly improves the disturbance estimation accuracy of the linear active disturbance rejection controller, leading to higher control precision and stronger robustness, thus demonstrating the effectiveness of the proposed control strategy.