Dielectric barrier discharge plasma is one of the most popular methods to generate nanthermal plasma, which is made up of a host of high-energy electrons, free radicals, chemically active ions and excited species, so it has the property of being prone to chemical reactions. Due to these unique advantages, the plasma technology has been widely used in the catalytic fields. Compared with the conventional method, the heterogeneous catalyst prepared by plasma technology has good dispersion and smaller particle size, and its catalytic activity, selectivity and stability are significantly improved. In addition, the interaction between plasma and catalyst can achieve synergistic effects, so the catalytic effect is further improved. The review mainly introduces the characteristics of dielectric barrier discharge plasma, development trend and its recent advances in catalysis; then, we sum up the advantages of using plasma technology to prepare catalysts. At the same time, the synergistic effect of plasma technology combined with catalyst on methanation, CH₄ reforming, NO_x decomposition, H₂O₂ synthesis, Fischer–Tropsch synthesis, volatile organic compounds removal, catalytic sterilization, wastewater treatment and degradation of pesticide residues are discussed. Finally, the properties of plasma in catalytic reaction are summarized, and the application prospect of plasma in the future catalytic field is prospected.

The dye wastewater produced in the printing and dyeing industry causes serious harm to the natural environment. TiO₂ usually shows photocatalytic degradation of dye under the irradiation ultravilet light rather than visible light. In this work, a large number of oxygen vacancies and Ti³⁺ defects were generated on the surface of the TiO₂ nanoparticles via Ar plasma. Compared with pristine TiO₂ nanoparticles, the as-obtained Ar plasma-treated TiO₂ (Ar-TiO₂) nanoparticles make the energy band gap reduce from 3.21 eV to 3.17 eV and exhibit enhanced photocatalytic degradation of organic dyes. The Ar-TiO₂ obtained exhibited excellent degradation properties of methyl orange (MO); the degradation rate under sunlight irradiation was 99.6% in 30 min, and the photocatalytic performance was about twice that of the original TiO₂ nanoparticles (49%). The degradation rate under visible light (λ > 400 nm) irradiation was 89% in 150 min, and the photocatalytic performance of the Ar-TiO₂ was approaching ~4 times higher than that of the original TiO₂ nanoparticles (23%). Ar-TiO₂ also showed good degradation performance in degrading rhodamine B (Rho B) and methylene blue (MB). We believe that this plasma strategy provides a new method for improving the photocatalytic activity of other metal oxides.

This study describes the decomposition of CO₂ using Dielectric Barrier Discharge (DBD) plasma technology combined with the packing materials. A self-cooling coaxial cylinder DBD reactor that packed ZrO₂ pellets or glass beads with a grain size of 1–2 mm was designed to decompose CO₂. The control of the temperature of the reactor was achieved via passing the condensate water through the shell of the DBD reactor. Key factors, for instance discharge length, packing materials, beads size and discharge power, were investigated to evaluate the efficiency of CO₂ decomposition. The results indicated that packing materials exhibited a prominent effect on CO₂ decomposition, especially in the presence of ZrO₂ pellets. Most encouragingly, a maximum decomposition rate of 49.1% (2-mm particle sizes) and 52.1% (1-mm particle sizes) was obtained with packing ZrO₂ pellets and a 32.3% (2-mm particle sizes) and a 33.5% (1-mm particle sizes) decomposing rate with packing glass beads. In the meantime, CO selectivity was up to 95%. Furthermore, the energy efficiency was increased from 3.3%–7% before and after packing ZrO₂ pellets into the DBD reactor. It was concluded that the packing ZrO₂ simultaneously increases the key values, decomposition rate and energy efficiency, by a factor of two, which makes it very promising. The improved decomposition rate and energy efficiency can be attributed mainly to the stronger electric field and electron energy and the lower reaction temperature.

Electrocatalysts are becoming increasingly important for both energy conversion and environmental catalysis. Plasma technology can realize surface etching and heteroatom doping, and generate highly dispersed components and redox species to increase the exposure of the active edge sites so as to improve the surface utilization and catalytic activity. This review summarizes the recent plasma-assisted preparation methods of noble metal catalysts, non-noble metal catalysts, non-metal catalysts, and other electrochemical catalysts, with emphasis on the characteristics of plasma-assisted methods. The influence of the morphology, structure, defect, dopant, and other factors on the catalytic performance of electrocatalysts is discussed.

Nitrogen oxides (NO_x) represent one of the main sources of haze and pollution of the atmosphere as well as the causes of photochemical smog and acid rain. Furthermore, it poses a serious threat to human health. With the increasing emission of NO_x, it is urgent to control NO_x. According to the different mechanisms of NO_x removal methods, this paper elaborated on the adsorption method represented by activated carbon adsorption, analyzed the oxidation method represented by Fenton oxidation, discussed the reduction method represented by selective catalytic reduction, and summarized the plasma method represented by plasma-modified catalyst to remove NO_x. At the same time, the current research status and existing problems of different NO_x removal technologies were revealed and the future development prospects were forecasted.

In the last few years, due to the large amount of greenhouse gas emissions causing environmental issue like global warming, methods for the full consumption and utilization of greenhouse gases such as carbon dioxide (CO₂) have attracted great attention. In this study, a packed-bed dielectric barrier discharge (DBD) coaxial reactor has been developed and applied to split CO₂ into industrial fuel carbon monoxide (CO). Different packing materials (foam Fe, Al, and Ti) were placed into the discharge gap of the DBD reactor, and then CO₂ conversion was investigated. The effects of power, flow velocity, and other discharge characteristics of CO₂ conversion were studied to understand the influence of the filling catalysts on CO₂ splitting. Experimental results showed that the filling of foam metals in the reactor caused changes in discharge characteristics and discharge patterns, from the original filamentary discharge to the current filamentary discharge as well as surface discharge. Compared with the maximum CO₂ conversion of 21.15% and energy efficiency of 3.92% in the reaction tube without the foam metal materials, a maximum CO₂ decomposition rate of 44.84%, 44.02%, and 46.61% and energy efficiency of 6.86%, 6.19%, and 8.85% were obtained in the reaction tubes packed with foam Fe, Al, and Ti, respectively. The CO₂ conversion rate for reaction tubes filled with the foam metal materials was clearly enhanced compared to the non-packed tubes. It could be seen that the foam Ti had the best CO₂ decomposition rate among the three foam metals. Furthermore, we used density functional theory to further verify the experimental results. The results indicated that CO₂ adsorption had a lower activation energy barrier on the foam Ti surface. The theoretical calculation was consistent with the experimental results, which better explain the mechanism of CO₂ decomposition.