The design of highly emissive and stable blue emitters for organic light emitting diodes (OLEDs) is still a challenge, justifying the intense research activity of the scientific community in this field. Recently, a great deal of interest has been devoted to the elaboration of emitters exhibiting a thermally activated delayed fluorescence (TADF). By a specific molecular design consisting into a minimal overlap between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) due to a spatial separation of the electron-donating and the electron-releasing parts, luminescent materials exhibiting small S₁–T₁ energy splitting could be obtained, enabling to thermally upconvert the electrons from the triplet to the singlet excited states by reverse intersystem crossing (RISC). By harvesting both singlet and triplet excitons for light emission, OLEDs competing and sometimes overcoming the performance of phosphorescence-based OLEDs could be fabricated, justifying the interest for this new family of materials massively popularized by Chihaya Adachi since 2012. In this review, we proposed to focus on the recent advances in the molecular design of blue TADF emitters for OLEDs during the last few years.

Truxene (10,15-dihydro-5H-diindeno[1,2-a;1′,2′-c]fluorene), which is a heptacyclic polyarene structure, has attracted a great deal of interest due to its exceptional solubility, high thermal stability and ease with which it may be modified. Over the years and thanks to the advances in the synthesis of truxene derivatives, the scope of applications of this attractive building block, initially limited to synthesis and photoluminescence, has nowadays been extended to organic electronics. This review aims at highlighting the benefits brought by the introduction of this rigid star-shaped molecule in different materials. Perspectives for this highly appealing molecule in future research will also be put forth.