This study investigates eutectic morphology transitions in Ni-Sn alloys using Bridgman directional solidification with a transition variable speed coupled with cellular automaton (CA) simulations. Steady-state solidification (0.1–2000 μm/s) produced only regular lamellar/rod-like eutectics, while velocity jumps triggered anomalous eutectic formation. As the drawing speed increased, the lamellar spacing decreased from ~3 μm to 0.4 μm, while the microhardness increased from ~426 HV to 500 HV. The experiments on Ni-Sn alloys revealed that anomalous eutectic morphologies form specifically at velocity transition interfaces (0.1–1000 μm/s), consistent with CA simulations showing destabilization of the lamellae, epitaxial growth of the Ni₃Sn phase, and decoupled nucleation of the α-Ni phase for the formation. The work defines a processing window for anomalous eutectic formation and provides mechanistic insights bridging undercooling and directional solidification regimes.

The transition from regular to anomalous eutectic structures critically impacts the mechanical properties of eutectic alloys. This study investigated the non-equilibrium solidification behavior of Ni-Sn alloys using Bridgman directional solidification coupled with Cellular Automaton (CA) simulations. Unlike deep undercooling methods, this approach can offer a solution by decoupling temperature gradient and growth velocity during the solidification process, revealing that anomalous eutectic formation occurs specifically at growth velocity transition zones, not during steady-state growth (0.1–2000 μm/s). CA simulations confirmed that velocity jumps destabilize regular lamellae, the Ni3Sn phase epitaxially grows along the substrate in a cellular manner, triggering independent α-Ni nucleation followed by Ni₃Sn encapsulation. This work identifies a distinct process window for anomalous eutectic formation and elucidates its decoupled nucleation mechanism, advancing non-equilibrium solidification theory.