Owing to its 100% theoretical salt rejection capability, membrane distillation (MD) has emerged as a promising seawater desalination approach to address freshwater scarcity. Ideal MD requires high vapor permeate flux established by cross-membrane temperature gradient (∆T) and excellent membrane durability. However, it’s difficult to maintain constant ∆T owing to inherent heat loss at feedwater side resulting from continuous water-to-vapor transition and prevent wetting transition-induced membrane fouling and scaling. Here, we develop a Ti₃C₂T_x MXene-engineered membrane that imparts efficient localized photothermal effect and strong water-repellency, achieving significant boost in freshwater production rate and stability. In addition to photothermal effect that circumvents heat loss, high electrically conductive Ti₃C₂T_x MXene also allows for self-assembly of uniform hierarchical polymeric nanospheres on its surface via electrostatic spraying, transforming intrinsic hydrophilicity into superhydrophobicity. This interfacial engineering renders energy-efficient and hypersaline-stable photothermal membrane distillation with a high water production rate under one sun irradiation.

Manipulating liquid is of great significance in fields from life sciences to industrial applications. Owing to its advantages in manipulating liquids with high precision and flexibility, electrowetting on dielectric (EWOD) has been widely used in various applications. Despite this, its efficient operation generally needs electrode arrays and sophisticated circuit control. Here, we develop a largely unexplored triboelectric wetting (TEW) phenomenon that can directly exploit the triboelectric charges to achieve the programmed and precise water droplet control. This key feature lies in the rational design of a chemical molecular layer that can generate and store triboelectric charges through agile triboelectrification. The TEW eliminates the requirement of the electric circuit design and additional source input and allows for manipulating liquids of various compositions, volumes, and arrays on various substrates in a controllable manner. This previously unexplored wetting mechanism and control strategy will find diverse applications ranging from controllable chemical reactions to surface defogging.