CuO nanoparticles, Cu2O/CuO and CuO/TiO2 nanocomposites exhibit excellent photocatalyst properties toward the degradation of methyl-orange and potassium-dichromate under the visible light irradiation.
In this work, we report the room temperature ferromagnetism in Sn1-xFexO2 and Sn1-xNixO2 (x = 0.00, 0.03 and 0.05) nano-crystalline powders. All the samples were prepared using co-precipitation method. X-Ray Diffraction (XRD), transmission electron microscopy (TEM), energy dispersive x-ray analysis (EDAX), UV-visible absorption spectroscopy and room temperature magnetization measurements were performed to study the crystal structure, morphology, elemental analysis, optical band gap and magnetic properties of Fe and Ni doped SnO2. TEM results depict the formation of spherically shaped and small sized nanoparticles of the diameter of ∼ 3 nm. The band gap energy of the Fe and Ni doped samples found to decrease with increasing their concentrations. The higher saturation magnetization was observed in low concentration Fe and Ni doped tin oxide.
We present a detailed study on the structural, electronic, and magnetic properties of chemically synthesized ( to 0.05) nanoparticles. X-ray diffraction and transmission electron microscope measurements were performed to analyze the crystal structure and morphology of nanoparticles. The energy dispersive x-ray analysis measurements were performed to check the possible presence of any impurity elements in the nanocrystals. The near edge x-ray absorption fine structure (NEXAFS) experiments at -edge and -edge were performed to probe the local environment of Sn and Co ions in the matrix. The NEXAFS at -edge, along with multiplet calculations, indicate that the Co is substituted at the Sn site in matrix with charge state and do not form metallic clusters and other oxide phases. The ferromagnetic nature of these materials was confirmed by x-ray magnetic circular dichroism and room temperature magnetization hysteresis loop measurements.
Magnesium oxide remained interesting from long time for several important phenomena like; defect induced magnetism, spin electron reflectivity, broad laser emission etc. Moreover, nanostructures of this material exhibited suitability for different kinds of applications ranging from wastewater treatment to spintronics depending upon their shape and size. In this way, researchers had grown nanostructures in the form of nanoparticles, thin films, nanotubes, nanowalls, nanobelts. Though nanoparticles and thin films are well known form of nanostructures and wide variety of synthesis approaches are available, however, limited methodology for other nanostructures are available. In order to grow these nanostructures in an optimized way an understanding of these methods is essential. Thus, this review article depicts an overview of various approaches for design of different kinds of nanostructures.