The absence of absolute dating in glacial deposits of the Paraná Basin prevents better understanding of the complete history of the Late Palaeozoic Ice Age in Western Gondwana and the climatic change that took place in the late Carboniferous. In this study, new U–Pb radiometric ages date the topmost glacial deposits of the Itararé Group at 307.7 ± 3.1 Ma (Kasimovian−Moscovian) and the base of post-glacial deposits of the Rio Bonito Formation at 298.8 ± 1.9 Ma (Ghzelian−Asselian). Correlation of glacial and post-glacial deposits of the Paraná Basin with other southwestern Gondwana basins shows that the end of the Late Palaeozoic Ice Age is asynchronous. Supplementary material: Laser ablation inductively coupled plasma mass spectrometry U–Pb zircon data and methods for the ash sample of the Itararé Group and the tonstein sample of the Rio Bonito Formation are available at https://doi.org/10.6084/m9.figshare.c.3278273 .

Zircon U-Pb geochronology was applied to investigate the provenance, depositional ages, and paleogeography of the southwestern Gondwana in detrital and ash fall sediments from Carboniferous to Jurassic succession of the southern Paraná Basin. Four detrital age populations suggest provenance from local and distal sources located to the south, southeast, and southwest: (i) Archean to Paleoproterozoic zircons from the Rio de La Plata Craton, Nico Peres and Taquarembó terranes; (ii) Grenvillian zircons from the basement of the Gondwanides and Namaqua–Natal belts; (iii) Neoproterozoic grains from the Don Feliciano Belt; and (iv) Phanerozoic populations from Paleozoic orogenic belts and related foreland systems in Argentina, as well as eroded units of the Paraná Basin. The paleogeographic reconstruction indicates an evolution in three distinct stages: (1) a gulf open to the Panthalassa Ocean during the Carboniferous; (2) an epicontinental sea with the rise of the Gondwanides Orogeny during the Permian; and (3) continental deposits controlled by an intra-plate graben system during the Triassic. Permian–Triassic volcanogenic zircons provide constrained maximum depositional ages and attested persistent volcanism, related to the Choiyoi magmatism and effects of the climate change episodes. During the Triassic, the extensional graben system recorded the uplift of the basement through regional northwest and northeast fault systems, and the recycling of Permian zircons, modifying source-to-sink relationships.

Orbital cycles are related to variations of Earth's orbit through time and exert profound control on glacial and interglacial climates due to changes in insolation. In this study, we aim to test whether orbital and millennial‐scale climate cycles conditioned the deposition of rhythmites in the southern Gondwana during the Late Paleozoic Ice Age (LPIA). We present the first cyclostratigraphic study based on X‐ray fluorescence records from a 27‐m‐thick interval of LPIA rhythmites in the southeastern border of the Paraná Basin, Brazil. TiO₂ and Fe₂O₃ records display cycles in the Milankovitch and millennial bands. Among millennial‐scale variability, there are strong signals suggesting cycles with periods similar to the ~2.4‐kyr Hallstatt heliomagnetic and the ~1.5‐kyr Dansgaard‐Oeschger cycles. We estimated an average sediment accumulation rate of 5.94 cm/kyr, which suggests that the rhythmites were deposited in a relatively distal setting, during deglaciation episodes paced by millennial‐scale climate cycles. We interpret variations in concentrations of the terrigenous components TiO₂ and Fe₂O₃ as indicative of glacial‐interglacial changes, reflected by advances and retreats of glaciers under drier and wetter climate conditions, respectively. Here we show that these high‐latitude glacial‐interglacial cycles were probably paced by short eccentricity, as previously suggested for Carboniferous cyclothems in low‐latitude deposits, and highlight the importance of millennial‐scale climate cycles at controlling glacially influenced deposition at high latitudes. Our results for the LPIA are similar to patterns seen in Pleistocene records.

Although the determination of remaining phosphorus (Prem) is simple, accurate values could also be estimated with a pedotransfer function (PTF) aiming at the additional use of soil analysis data and/or Prem replacement by an even simpler determination. The purpose of this paper was to develop a pedotransfer function to estimate Prem values of soils of the State of São Paulo based on properties with easier or routine laboratory determination. A pedotransfer function was developed by artificial neural networks (ANN) from a database of Prem values, pH values measured in 1 mol L-1 NaF solution (pH NaF) and soil chemical and physical properties of samples collected during soil classification activities carried out in the State of São Paulo by the Agronomic Institute of Campinas (IAC). Furthermore, a pedotransfer function was developed by regressing Prem values against the same predictor variables of the ANN-based PTF. Results showed that Prem values can be calculated more accurately with the ANN-based pedotransfer function with the input variables pH NaF values along with the sum of exchangeable bases (SB) and the exchangeable aluminum (Al3+) soil content. In addition, the accuracy of the Prem estimates by ANN-based PTF were more sensitive to increases in the experimental database size. Although the database used in this study was not comprehensive enough for the establishment of a definitive pedotrasnfer function for Prem estimation, results indicated the inclusion of Prem and pH NaF measurements among the soil testing evaluations as promising ind order to provide a greater database for the development of an ANN-based pedotransfer function for accurate Prem estimates from pH NaF, SB, and Al3+ values.

Minerals are the fundamental record of abiotic processes over time, while biominerals are one of the most common records of life due to their easy preservation and abundance. However, distinguishing between biominerals and abiotic minerals is challenging due to the superimposition and repetition of geologic processes and the interference of ubiquitous and diverse life on Earth's surface and crust. Mineral dubiofossils, being potential outcomes of both abiotic and biotic environments, emerge as valuable entities that can contribute significantly to the understanding of this issue, facilitating the testing and refinement of biogenicity criteria. The aim of this contribution is to decipher the origin and history of branched mineralized structures that were previously considered mineral dubiofossils from the Pennsylvanian of the Paraná Basin, Brazil. While this material has different forms and refers to biological aspects, it is challenging to associate it with any known fossil group due to the overlapping geological processes occurring in a transitional deposit of Rio do Sul Formation (Itararé Group of the Paraná Basin), particularly in close proximity to a sill from the Serra Geral Group (Lower Cretaceous), which has undergone thermal effects. Given the absence of attributes essential for supporting the initial hypotheses proposing the material as a potential set of sponge spicules or a result of contact metamorphism in Pennsylvanian turbidites, the objects are now investigated as mineral dubiofossils. To address this challenge, we have developed a descriptive protocol for dubiofossils, building upon prior research in the field. This protocol evaluates the following aspects: (1) morphology, texture, and structure; (2) relationship with the matrix; (3) composition; and (4) context. This is done by assessing indigeneity and syngenicity and comparing the specimens with abiotic and biotic products. Applying this protocol to our samples revealed a wide range of morphologies with internal organization, predominantly composed of calcite with impurities such as iron, magnesium, aluminum, and oxygen. The inferred indigeneity suggests the presence of these minerals concurrently with or prior to the intrusion of the sill. Extensive comparisons were made between the studied samples and a broad spectrum of abiotic minerals, as well as controlled, induced, and influenced biominerals from similar contexts. These comparative analyses encompassed sponge spicules; sea urchin and algae skeletons; minerals induced or influenced by fungi, bacteria, and microbial mats; and inorganic pre- and synsedimentary–eodiagenetic minerals like evaporites, springs, and other precipitates, and mesodiagenetic–metamorphic crystals. Despite this comprehensive analysis, no hypothesis emerged as significantly more likely than others. The comparative analysis did allow us to exclude the possibility of the samples being controlled biominerals due to their patternless diversity of morphologies, as well as purely thermometamorphic in origin due to their branched elongated forms. The occurrence of these structures suggests a complex history: a syn-depositional or eodiagenetic origin of some carbonate or sulfate (gypsum, ikaite, dolomite, calcite, aragonite, siderite), potentially associated with the presence of microbial mats, which may have served as templates for mineralization and mediated mineral growth. Mesodiagenesis could have further modified the occurrence through processes such as mineral stabilization, agglutination, aging, and growth. However, the primary agent responsible for the formation of the dubiofossil was the Cretaceous intrusion, which dissolved and replaced the initial minerals, resulting in the precipitation of calcite. Throughout these steps, a combination of physical–chemical and biological reactions, influenced by intrinsic matrix characteristics, organic matter content, and distance from the intrusive body, may have contributed to the heightened morphological complexity observed, thus corroborating the origin of the material becomes even more challenging. Consequently, both the hypotheses pertaining to the formation of biotic and abiotic sulfates and carbonates remain plausible explanations, hence sustaining the classification of the material as a dubiofossil. This material illustrates how dubiofossils can be a result of a complex history and overlapping geological processes. It also highlights the difficulty in differentiating biominerals from abiotic minerals due to the scarcity of biogenicity arguments.