This study investigated sustainable activation strategies for residual slag micro powder derived from recycled waste concrete aggregates, aiming to advance circular economy principles in construction materials. An experimental study was carried out to explore the activation mechanisms of slag micro powder from recycled waste concrete aggregates to enhance its utility in building materials. Three methods—mechanical grinding, high-temperature calcination, and mechanical grinding–thermal activation—were evaluated comparatively. The results showed high-temperature calcination at 750 °C for 10 min proved most effective, achieving a 95.85% activity index. High-temperature calcination may contribute to the release of active SiO₂ and Al₂O₃ substances of slag micro powder, thereby improving the hydration performance of slag micro powder and its cement mortar’s compressive strength. The flexural strength of cement mortar after different activation treatments was also analyzed. Mechanical grinding alone showed limited benefits, only achieving a less than 65.59% activity index, while the combined method negatively impacted the mechanical properties of cement mortar samples. An SEM (scanning electron microscope) and EDS (energy dispersive X-ray spectrometer) microstructural analysis supported these findings, highlighting enhanced hydration product formation after calcination at 750 °C for 10 min. This work may contribute to sustainable construction practices through the resource-efficient utilization of industrial by-products.

Superabsorbent polymers (SAPs) are widely employed as an internal curing agent to enhance the durability and shrinkage–cracking resistance of concrete. However, while its macroscopic effects on concrete properties (e.g., strength reduction) have been documented, the nanoscale mechanisms governing the mechanical behavior of calcium silicate hydrate (C-S-H) gel in SAP-modified concrete remain poorly understood. This knowledge gap limits the optimization of SAP content for balancing durability and strength, a critical challenge in high-performance concrete design. In this paper, we address this scientific problem by combining experimental characterization and molecular dynamics (MD) simulations to systematically investigate how SAP-induced pore structure modifications dictate the mechanical performance of C-S-H gel. First, we analyzed the effects of SAP on concrete pore structure and compressive strength, revealing its role in refining capillary pores into gel pores. Next, MD simulations were employed to construct C-S-H gel models with controlled pore size distributions at three SAP contents (0.2%, 0.3%, and 0.5%), to establish a quantitative relationship between pore characteristics and material performance. The results reveal that pores of ~0.74 nm diameter, predominantly located in weak interfacial regions, critically govern the mechanical behavior of C-S-H gel. At 0.2% SAP content, the C-S-H gel exhibits the highest bulk modulus (10.61 GPa) and optimal mechanical properties, whereas 0.3% SAP leads to a dominant pore cluster at 1.12 nm, resulting in significant reductions in bulk modulus (30.8%), shear modulus (29%), and Young’s modulus (22.3%). These findings establish a quantitative pore-property relationship, providing a mechanistic basis for tailoring SAP content to enhance both durability and mechanical performance in concrete, ultimately advancing the design of longer-lasting infrastructure.

Drying shrinkage cracking of hydraulic cementitious materials, induced by moisture loss under varying environmental conditions, significantly compromises structural durability. The utilization of construction waste powder (CWP) in cement composites presents a sustainability opportunity, but its impact on shrinkage behavior remains poorly understood. This study aims to systematically investigate the drying shrinkage characteristics of cement-CWP composite mortar and to identify optimal mix proportions and curing conditions for shrinkage control. A series of experiments were conducted on mortar specimens with varying water-to-binder ratios (W/B = 0.45, 0.50, 0.55) and CWP incorporation rates (0, 5%, 10%, 20%). Three curing regimes were employed: outdoor curing, standard curing (20 °C, 95% RH), and outdoor film curing. Drying shrinkage was monitored over time. Key findings indicate that the optimal CWP content for shrinkage mitigation is 10%. Excessive CWP (>10%) induces a “weak bonding” effect, leading to an increase in shrinkage due to reduced cohesion. Increasing the W/B ratio to 0.55 effectively reduced shrinkage, with the minimum shrinkage value observed at this ratio. Among curing methods, outdoor film demonstrated superior performance in maintaining moisture and suppressing shrinkage. Predictive modeling revealed that the logarithmic model in accurately capturing the nonlinear evolution of shrinkage over time, effectively reflecting the influences of CWP content, W/B ratio, and curing condition. The drying shrinkage of cement-CWP composite mortar can be effectively optimized by incorporating 10% CWP, utilizing a W/B ratio of 0.55, and implementing outdoor film curing. This paper reveals, for the first time, the dual-mechanism regulation of early-age drying shrinkage behavior in cement-based materials by CWP as a supplementary cementitious material and establishes a shrinkage prediction model applicable to various mix proportions and curing conditions, offering practical strategies for enhancing the durability of sustainable construction materials utilizing construction waste powder.

FRP-confined gangue aggregate concrete partially filled steel tubes (CGCPFTs) can not only effectively enhance the performance of coal gangue concrete, but also fully exploit the elastic-plastic mechanical behavior of the steel tubes. However, research on theoretical models that can describe their mechanical properties is yet to be conducted. To fill this gap, theoretical models for structural design and analysis were proposed for CGCPFTs. For the analytical model, based on the available experimental data, a prediction method for the stress–strain behavior of the gangue aggregate concrete in CGCPFTs, which is confined only by FRP and partly confined by both FRP and the steel tubes, was first proposed. Additionally, the condition for the synergetic deformation of the two confined states of gangue aggregate concrete within the CGCPFT was proposed. Based on the condition, an iterative incremental process was developed which subsequently allows for the theoretical calculation of the load–displacement curve for the CGCPFT under monotonic axial compression. For the design model, by introducing the constraint contribution coefficient of the steel tube, the existing closed-loop calculation formula for the stress–strain relationship of FRP-confined concrete was revised. Furthermore, by expressing the axial and lateral stresses of the steel tube as a unified circumferential effect on the concrete, the calculation methods for the ultimate strength and strain in the closed-loop formula were redefined, thus achieving the prediction of the stress–strain behavior of CGCPFTs. The comparison with the test data obtained by the author and their team revealed that both the analysis and design models could provide accurate predictions.

This study systematically investigated the alkali activation behavior of construction waste micro-powder (CWM) to develop a low-carbon, high-performance cementitious material. The activator formulation was optimized, the hydration thermodynamics were analyzed, and a kinetics model was constructed to reveal the reaction mechanism. The composite activator (sodium silicate and Portland cement) exhibited a significant synergistic effect, outperforming single activators. The optimal ratio was determined: 40% CWM, 60% Portland cement, and 8% water glass (modulus 1.0), which balances the system’s alkalinity and silicate modulus. Thermogravimetric analysis revealed a notable net weight gain at 3 days, indicating an ongoing secondary hydration reaction. By 7 days, the main hydration was complete, accompanied by microstructural densification, which confirmed the efficiency of the composite activator. A key contribution was the successful application of the Krstulović–Dabić (KD) model to quantify the hydration mechanism. The hydration process evolved sequentially through nucleation and growth (NG, dominant before 0.05~0.15 h), phase boundary reaction (I), and diffusion (D). The period of 0.21–50 h was governed by both I and D, after which D became the sole rate-limiting step. The model yielded the rate constants (K_NG, K_I, K_D), Avrami exponent (n), and transition points (α1, α2), providing a kinetic explanation for the ‘early strength and rapid hardening’ characteristic. In conclusion, this work establishes a material design framework guided by activator optimization, supported by thermodynamics, and explained by kinetics. The KD model proves to be a powerful tool for deciphering the hydration behavior of alkali-activated CWM, offering theoretical guidance for developing sustainable cementitious materials with controllable performance.