Original compositions of electrical ceramics have been developed and tested using marshalite and wollastonite as raw materials. An analysis of the equilibrium states of the created porcelain masses at different temperatures in Na₂O-Al₂O₃-SiO₂ and K₂O-Al₂O₃-SiO₂ systems was carried out. The amount of melt in these systems was calculated based on equilibrium flux curves. The characteristics of the sintering process of the masses were identified. A scheme for the formation of key secondary needle-like mullite during the thermal treatment of the masses was outlined and the temperature intervals for the formation of intermediate compounds were found. X-ray diffraction patterns and micrographs of the synthesized samples were decoded, and the phase composition and microstructure of the samples were analyzed. The effective influence of silica component dispersion on the mineral formation processes during the sintering of the porcelain masses in model samples of feldspar compositions with quartz sand and marshalite was noted. The optimal firing temperatures for full mineral formation and structure formation have been determined, as well as the physical–mechanical and dielectric properties of the obtained ceramic samples.

Original compositions of electrical ceramics have been developed and tested using marshallite and wollastonite as raw materials. An analysis of the equilibrium states of the created porcelain masses at different temperatures in the Na2O-Al2O3-SiO2 and K2O-Al2O3-SiO2 systems has been carried out. The amount of melt in these systems has been calculated based on the equilibrium flux curves. The characteristics of the sintering process of the masses have been identified. A scheme for the formation of the very important secondary needle-like mullite during thermal treatment of the mass has been outlined, and the temperature intervals for the formation of intermediate compounds have been found. X-ray diffraction patterns and micrographs of the synthesized samples have been decoded, and the phase composition and microstructure of the samples have been analyzed. The effective influence of the dispersion of the silica component on the mineral formation processes during the sintering of porcelain masses on model samples of compositions of feldspar with quartz sand and marshallite has been noted. The optimal firing temperatures for full mineral formation and structure formation have been determined, as well as the physical-mechanical and dielectric properties of the obtained ceramic samples.