Herein, we fabricated a starch-based flexible coating for food packaging papers with excellent hydrophobicity and antimicrobial properties. FTIR (Fourier transform infrared) and XRD (X-ray diffraction) spectra revealed the homogeneous dispersion of the ZnO nanoparticles (NPs) in the composite film within 5% ZnO NP dosage. SEM (scanning electron microscope) and AFM (atomic force microscope) micrographs confirmed the increased roughness on the composite film with the increased dosages of ZnO NPs. Hydrophobic characteristics showed that dramatic enhancement was obtained in the values and stabilities of DCAs (dynamic contact angles) in the resultant film and coated paper. TG (thermogravimetry) results demonstrated the increased thermal stabilities of the composite films. Significantly, a decreased water vapor transmission rate was observed in the coated paper. When 20% guanidine-based starch and 2% CMC (carboxy methyl cellulose) was added, a flexible coating with excellent antimicrobial activity towards Escherichia coli can be obtained. Furthermore, the migration of ZnO NPs into the food simulants was well below the overall migration legislative limit. The resultant starch-based flexible composite film and coated paper established an effective approach to develop a green-based material for food packaging applications.

Herein, the chitosan-based (CS) composite film was fabricated via a simple and efficient blending approach by adding poplar hot water extract (HWE), bentonite (BT) and chitosan. The addition of HWE largely improved the UV blocking ability and antioxidant properties of the resultant composite film, and simultaneously a tortuous path was constructed within the chitosan matrix to enhance the water vapor and oxygen barriers after the addition of BT. Specially, the content of HWE at 10 wt % gave a greatly decreased UV light transmittance at 280 nm to the CS-BT-HWE composite film that was 99.36% lower than that of CS-BT film, and the oxidation resistance was 9.65 times higher than that of CS-BT. The mechanical properties and surface morphological observation evaluated by scanning electron microscopy (SEM) and scanning probe microscope (SPM) confirmed the film had a denser structure. The internal chemical structure analyzed using solid state NMR, FTIR and X-ray spectra exhibited the resultant Maillard structure and strong hydrogen bonding that contributed to the improved mechanical properties. Overall, the as-prepared composite film has great potential as food packaging materials, and also provides a high-efficient utilization pathway for HWE.