Fusel oil (FO) is one of the by-products of the sugar-alcohol industry, which has application as an additional source of higher alcohols for production of esters with flavoring, fuels and lubricants properties, as well as additives in petroleum-based fuels and in pesticide formulations. Thus, this review is focused on the characteristics of FO and its applications as an acyl acceptor in transesterification and esterification reactions for esters production, its addition to fossil fuels, and the herbicidal and fungicidal potential of the compounds presented in its chemical composition. The operating conditions of the process, results obtained, and patented applications in the food, cosmetic, transportation and agricultural sectors are also reported and discussed. Furthermore, main trends, challenges and recommendations are proposed in order to overcome the disadvantages of applying FO in the reported sectors, as well as alternatives for the development of new lines of research are suggested.

This study evaluated the oil content obtained from andiroba seeds by pressurized n-propane at different conditions of temperature (25, 35, and 45 °C) and pressure (40, 60, and 80 bar), and conventional extraction technique using n-hexane as the solvent. Kinetic extraction curves were fitted using Sovová’s mathematical model. The chemical characterization of the oil was reported as well as the protein content in the extraction by-product. Pressurized extractions conducted at 25 °C provided the highest oil recovery (~45 wt%) from the seeds. The increase in pressure at 25 ºC favored obtaining oil with higher Stigmasterol contents, however, the Squalene content was higher in the oil obtained at 40 bar. The oils with the highest concentration phenolic compounds and antioxidant activity were obtained at 80 bar. Extraction with n-propane provided oils with higher levels of phenolic compounds, however, with antioxidant activity similar to conventional extraction. For all evaluated extractions, the product showed a predominance of oleic and palmitic acids, with similar values of oxidative stability. The extraction of the by-product with the highest soluble protein content was obtained under mild processing conditions (25 °C and 40 bar) with n-propane.

The present work aimed to obtain and characterize sunflower seed oil (SO) enriched with compounds from turmeric rhizome (TR). For this purpose, the enriched oil was obtained from two strategies: extraction of the compounds from TR using SO as solvent (ESO) and simultaneous extraction of SO and TR compounds using ethyl acetate as solvent (ESOS). In these strategies, the effect of time (15 and 30 min) and temperature (60 and 70 °C) on the enrichment in relation to the curcuminoids content was determined. Evaluation of phytochemicals such as total phenolic compounds (TPCs), phenolic compound profile and fatty-acid profile and bioactivity by antioxidant potential (AP) was carriedoutin the enriched oils and in the SO;mean while, oxidative stability and cytotoxicity were evaluated using HaCaT (human immortalized keratinocyte) cells. From the results obtained, higher contents of curcuminoids (510 mg/100 g oil) were observed in the oil obtained from simultaneous extraction (ESOS) in a shorter time and lower temperature (15 min and 60 °C), and similar behavior was found for the content of phenolic compounds and antioxidant potential. The profile of phenolic compounds revealed the presence of phenolic acids, curcuminoids and terpenes in the composition of the enriched oils, which increased oxidative stability. The oils obtained did not show any cytotoxic effect against the cells tested, confirmed by the high survival rate (>88%) after 48 h of exposure.

Desenvolvimento de sorvete vegano de chocolate formulado com batata doce e leite de coco / Development of vegan chocolate ice cream formulated with sweet potatoes and coconut milk

The valorization of byproducts such as defatted meal (DM) is essential for the implementation of a biorefinery structure and can be achieved through the application of emerging technologies, such as pressurized liquid extraction. This work aimed to apply pressurized liquid extraction to obtain products derived from the DM of crambe (Crambe abyssinica Hochst) seeds. The experiments investigated the effect of ethanol percentage in the hydroalcoholic solvent (25%, 50% and 75%, v/v) on the mass extract yield (MEY) and on the composition of the products obtained: phytochemical extract (PE) and processed flour (PF). The PE obtained using 25% ethanolic solvent had the highest MEY (23.48 wt%) and phenolic compounds, composed of caffeic, gallic and ferulic acids, which conferred activity against the fungus C. albicans. The solvents tested did not influence the content of soluble proteins. The solvent with 75% ethanol promoted the highest levels of glucosinolates (258.94 μmol/g) and tannins (8.80 mg/g) in the PE, reducing 96% and 98% of these contents in the PF produced. The PF obtained in the extraction with 75% ethanol contained phenolic compounds (~23 mg/100 g), dietary fibers (54.25 g/100 g) and soluble proteins (26.39 wt%), mainly composed of glutelin fraction. The PF also presented adequate functional properties, such as water solubility and absorption, which suggest potential use in pet food formulations.