The location selection of distribution centers is one of the important strategies to optimize the logistics system. To solve this problem, under certain environment, this paper presents a new multicriteria decision-making method based on ELECTRE I. The proposed method helps decision-makers to select the best location from a given set of locations for implementing. After having identified decision-makers, the criteria, and the set of locations, the factors influencing the selection are analyzed in order to identify the best location. A sensitivity analysis is then performed to determine the influence of criteria weights on the selection decision. The strength of the proposed method is to incorporate decision-makers’ preferences into the decision-making process. In addition, the proposed method considers both quantitative and qualitative criteria. Finally, the selected solution is validated by both tests of concordance and discordance simultaneously. A case study is provided to illustrate the proposed method.