Owing to the depletion of bauxite and increasing demand for alumina, calcination methods for extracting alumina from coal fly ash (CFA) were developed. However, these methods have disadvantages such as the need for high temperatures and the emission of toxic gases. Hence, in this study, Al₂O₃ was extracted from CFA via low-temperature potassium bisulfate calcination technology. Effects of the potassium bisulfate amount, calcination temperature, and calcination time on the alumina extraction efficiency were investigated using X-ray diffraction, thermal gravimetry, scanning electron microscopy, differential scanning calorimetry, and energy-dispersive spectroscopy. It was found that this technique could recover alumina efficiently, and potassium bisulfate significantly contributed to the degradation of mullite and corundum phases. Al₂O₃ in CFA was converted into soluble K₃Al(SO₄)₃. With a KHSO₄/Al₂O₃ molar ratio of 7:1, calcining temperature of 230 °C, and calcining time of 3 h, the alumina extraction efficiency reached a maximum of 92.8%. The Avrami–Erofeev equation showed the best fit with the kinetic data for the low-temperature calcination of CFA with KHSO₄. The activation energy was 28.36 kJ/mol.

The utilization of coal fly ash (CFA) as a soil conditioner has been a research hotspot in recent years. In this paper, the continuity and stability of the yield-increasing effect of a fly ash-based soil conditioner were investigated through field trials for three consecutive years. The yield-increasing effect and applicability were also investigated by planting a variety of crops in different types of soil. Field test results revealed that the new fly ash-based soil conditioner had wide adaptability and stability under the condition of reducing the application of traditional fertilizers by 20%. For corns grown in castano-cinnamon soil and dark brown soil, the application of the new fly ash-based soil conditioner for three consecutive years has steadily increased the yield by more than 10%. The yield of wheat planted in castano-cinnamon soil also increased by 15%. Additionally, considering that heavy metals (HMs) contained in the fly ash-based soil conditioner may cause environmental contamination, this paper calculated and analyzed the bio-concentration factor (BCF) and the translocation factor (TF) of Cr, As, Cd, Hg and Pb in the corn experimental fields. The results showed that the five heavy metals were not significantly enriched in various parts of the corn stalk after application of the soil conditioner, and there was temporarily no environmental risk in terms of returning straws to the field or raising livestock.