To enhance the utilization efficiency of coal gangue aggregate, coarse aggregates are chemically modified with 5% sodium silicate solution. The effects of this modification on the compressive strength and microstructural characteristics of concrete are systematically investigated through integrated macro-testing and micro-characterization. By evaluating the compressive performance of modified coal gangue concrete blocks, the optimal mix ratio of each strength grade of blocks is determined. Experimental results indicate that the apparent density, water absorption, and crushing index of the modified coal gangue coarse aggregate exhibit better mechanical properties than the control group. The modified coal gangue coarse aggregate demonstrates improved mechanical performance, with the compressive strength of 28-day concrete showing a 15.3% increase relative to the control group. Furthermore, using a sodium silicate solution effectively enhances the interface transition zone’s performance between coal gangue coarse aggregate and cement mortar, improving the compactness of this interface. The modified coal gangue concrete blocks exhibit higher compressive strength than the original material. When the substitution rate remains constant, the compressive strength of modified coal gangue concrete decreases with increasing water–cement ratio. Similarly, at a constant water–binder ratio, compressive strength decreases with higher modified gangue aggregate replacement. Finally, compressive tests are conducted on masonry constructed with hollow blocks of strength grades MU7.5, MU10, and MU15. Then, a calculation model for the average compressive strength of modified coal gangue concrete hollow block masonry is proposed, providing theoretical support for its engineering application.

Earthen materials are attractive sustainable building solutions due to their low embodied energy and ecological benefits. However, their inherent weaknesses, such as low strength and poor durability, severely restrict modern engineering applications. Traditional physical or chemical modification methods struggle to balance significant improvement in mechanical performance with the preservation of their core sustainable attributes. To overcome this long-standing challenge, this study proposes a paradigm-shifting solution: a prefabricated monolithic lattice–earth composite wall structure. This system abandons the single-material-centered modification approach. Instead, through macroscopic system-level composite design, reinforced concrete lattices and earthen blocks are prefabricated into integral wall panels in a factory. These panels then work collaboratively with the peripheral frame through reliable integral connections. Via quasi-static tests and theoretical analysis on four scaled wall specimens with different design parameters, this study systematically reveals the working mechanism and performance regulation principles of this composite system. The core findings indicate: (1) The system achieves multiple seismic defense lines and a controllable energy dissipation path through a sequential damage mechanism: “earthen material cracking and friction → lattice yielding and energy dissipation → final defense by the frame.” (2) The ratio of the equivalent lateral stiffness of the prefabricated wall panel to the stiffness of the outer frame is a key dimensionless design parameter controlling the failure mode (ductile shear or brittle bending), and the lattice configuration is an effective means to adjust this parameter. (3) Based on tests and an equivalent stiffness model, quantitative design guidelines are proposed, focusing on optimizing lattice density (recommended: 3–4 lattice columns), limiting the aspect ratio (preferably ≤1.5), and ensuring “strong connections.” This study demonstrates that the system, without sacrificing the intrinsic sustainable advantages of earthen materials, successfully endows them with high performance, meeting modern seismic code requirements and potential for prefabricated construction through system integration innovation. It provides a new path with theoretical foundation and practical feasibility to resolve the core contradiction in the modernization of traditional earthen buildings—the incompatibility between ecological attributes and engineering performance. This lays an important foundation for developing next-generation high-performance green building structural systems.