This work discusses the regional geological and geophysical datasets (potential field data coupled with seismic lines) available across the Eastern Brazilian Continental Margin and addresses tectonic models that have been applied to the geological interpretation of the Vitória-Trindade Chain (VTC). New magnetic data acquired in the Trindade Island is combined with compiled petrological data and geological maps to propose a stratigraphic column with radiometric control for the volcanic sequences. The gravity and magnetic anomaly maps were integrated with regional seismic profiles extending from the continental platform towards the oceanic crust, showing the geomorphology of the Abrolhos Volcanic Complex (AVC) and the VTC. A detailed geological mapping of the Trindade Island was complemented by magnetometric profiles acquired on the island. The magmatic episodes identified in the Trindade Island within different volcano-stratigraphic sequences are, geochronologically, dated by ⁴⁰Ar/³⁹Ar method as Late Neogene to Quaternary (Pliocene/Upper Pleistocene) and indicate intrusive and extrusive igneous rocks formed on the Mesozoic (Cretaceous) oceanic crust. Models for the emplacement of these volcanic rocks on much older oceanic crust include hotspots and leaking fracture zones. The presence of flat tops as observed in the volcanic banks and seamounts along the Vitória-Trindade volcanic chain indicate abrasion of much higher volcanic edifices that now form the isolated islands in the Trindade-Martin Vaz Archipelago. Geological mapping and detailed magnetometric surveys suggest different rock properties for distinct volcanic episodes that formed the Trindade Island. The remarkable pattern of magnetic anomalies trending NE-SW in the deep-water region of the Espírito Santo Basin, eastwards of the AVC, suggests that the linear chain of volcanic edifices in the VTC may be associated with mantle anomalies caused by a hotspot or plume that was influenced by the E-W direction of leaking transform fracture zones. Abbreviation: Abrolhos Volcanic Complex (AVC); Vitória-Trindade Chain (VTC)

Several alkaline massifs on inland southeastern Brazil extend offshore, roughly parallel to ~20° S, through a seamount chain of the Vitoria-Trindade ridge. This paper presents the first extensive work on the Martin Vaz volcano through whole-rock and Sr and Nd isotopic composition of volcanic and subvolcanic lithotypes from the Martin Vaz Island, located at the easternmost of this volcanic chain. These alkaline rocks were generated during the Plio-Pleistocene (~0.47 My, ⁴⁰Ar/³⁹Ar dating in whole-rock) and represent the crystallization of sodic magmas of nephelinitic composition that evolved through fractional crystallization towards phonolites. Calculations from P–T_Liquidus using PELE software show temperatures of 1045°C and 818°C, viscosity of 2.47 log Poise and 5.02 log Poise, and densities of 2.57 g/cm³ and 2.26 g/cm³ for nephelinite and phonolite, respectively. Like in Trindade Island, the nephelinitic volcanism in Martin Vaz may represent a Strombolian and/or Hawaii-type eruption due to low viscosity magma according to its physical properties whereas phonolitic intrusions present higher viscosity characteristics forming lava domes. The ⁸⁷Sr/⁸⁶Sr (~ 0.703800) and ¹⁴³Nd/¹⁴⁴Nd (~ 0.512750) ratios of lavas from the seamounts and Martin Vaz do not vary significantly, pointing to partial melting process from a homogeneous mantle source showing isotope signature close to HIMU. Beside the restrict variation on these isotopic ratios, a conspicuous enrichment in incompatible trace elements, mainly LREE, indicates that metasomatism is a recent process and not a long-term source characteristic. Non-modal partial melting models (fractional melting and batch melting) suggest that the source of the Martin Vaz magmatism is consistent with the garnet-lherzolite mantle stability field (>90 km depth; Tb/Yb >0.7), generated about 3.0 GPa by very small degree of partial melting of an enriched wet mantle source (F = 0.03–0.04) with 2.5 wt. % of CO₂.