Rheological measurements and FTIR spectroscopy were used to characterize different doughs, obtained by commercial and monovarietal durum wheat flours (Cappelli and Karalis). Rheological frequency sweep tests were carried out, and the Weak Gel model, whose parameters may be related to gluten network extension and strength, was applied. IR analysis mainly focused on the Amide III band, revealing significant variations in the gluten network. Compared to the other varieties, Karalis semolina showed a higher amount of α-helices and a lower amount of β-sheets and random structures. Spectroscopic and rheological data were then correlated using Partial Least Squares regression (PLS) coupled with the Variable Importance in Projection (VIP) technique. The combined use of the techniques provided useful insights into the interplay among protein structures, gluten network features, and rheological properties. In detail, β-sheets and α-helices protein conformations were shown to significantly affect the gluten network's mechanical strength.

The present work shows the experimental evidence carried out on a pilot scale and demonstrating the potential of Cannabis sativa L. by-products for biogas production through anaerobic digestion. While the current state-of-the-art tests on anaerobic digestion feasibility are carried out at the laboratory scale, the here described tests were carried out at a pilot-to-large scale. An experimental campaign was carried out on hemp straw residues to assess the effective performance of this feedstock in biogas production by reproducing the real operating conditions of an industrial plant. An organic loading rate was applied according to two different amounts of hemp straw residues (3% wt/wt and 5% wt/wt). Also, specific bioenhancers were used to maximize biogas production. When an enzymatic treatment was not applied, a higher amount of hemp straw residues determined an increase of the median values of the gas production rate of biogas of 92.1%. This reached 116.6% when bioenhancers were applied. The increase of the specific gas production of biogas due to an increment of the organic loading rate (5% wt/wt) was +77.9% without enzymatic treatment and it was +129.8% when enzymes were used. The best management of the biodigester was found in the combination of higher values of hemp straw residues coupled with the enzymatic treatment, reaching 0.248 Nm³·kg_{volatile solids}⁻¹ of specific biogas production. Comparisons were made between the biogas performance obtained within the present study and those found in the literature review coming from studies on a laboratory scale, as well as those related to the most common energy crops. The hemp straw performance was similar to those provided by previous studies on a laboratory scale. Values reported in the literature for other lignocellulosic crops are close to those of this work. Based on the findings, biogas production can be improved by using bioenhancers. Results suggest an integration of industrial hemp straw residues as complementary biomass for cleaner production and to contribute to the fight against climate change.

This paper reports outcomes of life cycle assessments (LCAs) of three different oleaginous bioenergy chains (oilseed rape, Ethiopian mustard and cardoon) under Southern Europe conditions. Accurate data on field practices previously collected during a three-year study at two sites were used. The vegetable oil produced by oleaginous seeds was used for power generation in medium-speed diesel engines while the crop residues were used in steam power plants. For each bioenergy chain, the environmental impact related to cultivation, transportation of agricultural products and industrial conversion for power generation was evaluated by calculating cumulative energy demand, acidification potential and global warming potential. For all three bioenergy chains, the results of the LCA study show a considerable saving of primary energy (from 70 to 86 GJ·ha⁻¹) and greenhouse gas emissions (from 4.1 to 5.2 t CO₂·ha⁻¹) in comparison to power generation from fossil fuels, although the acidification potential of these bioenergy chains may be twice that of conventional power generation. In addition, the study highlights that land use changes due to the cultivation of the abovementioned crops reduce soil organic content and therefore worsen and increase greenhouse gas emissions for all three bioenergy chains. The study also demonstrates that the exploitation of crop residues for energy production greatly contributes to managing environmental impact of the three bioenergy chains.