As one of the promising room temperature nuclear radiation detection materials, the all-inorganic perovskite CsPbBr3 single crystal has been receiving much attention in recent years. Even though the performance of the CsPbBr3 detector is improving continuously, the disadvantages of detection instability have not been solved fundamentally, and this instability is mainly caused by ionic migration in the CsPbBr3 single crystal itself. In this paper, a reasonable ionic migration model is proposed based on an in-depth study of the current hysteresis phenomenon and ionic migration mechanism in the Ti/CsPbBr3/Ti detector. The model shows that the ions migrate to the anode or cathode under an external electric field, and the accumulated ions subsequently form an inverted internal electric field inside the crystal and carrier transport barriers at the metal–semiconductor interface simultaneously. The photoelectric characteristic and ionic migration activation energy (Eaion) fitting results also prove the rationality of the ionic migration model. Furthermore, the ionic migration model can also be used to explain the left-shift of the energy response peak and the decrease in the normalized charge collection efficiency in the Ti/CsPbBr3/Ti detector. This paper systematically investigates the intrinsic origin of migrated ions and the influence of ionic migration on detection stability, which will provide a potential solution to improve detection stability by suppressing ionic migration in the near future.
The drilling core sampling and chemical analysis method for the quantitative determination of solid mineral deposits has several drawbacks, including a low core drilling efficiency, a high core sampling cost, and a long chemical analysis cycle. In current uranium quantification practices, advanced techniques have been developed to preliminarily determine the formation of uranium content based on the interpretation results of natural -ray total logging. However, such methods still require supplementary core chemical analysis to derive the uranium–radium–radon balance coefficient, which is then used for equilibrium correction to obtain the true uranium content within the uranium-bearing layer. Furthermore, conventional prompt neutron time spectrum logging is constrained by low count rates, resulting in slow logging speeds that fail to meet the demands of practical engineering applications. To address this, this study proposes a uranium quantification method that corrects the natural -ray total logging using prompt neutron time spectrum logging. Additionally, a calibration parameter determination method necessary for quantitative interpretation is constructed. Experimental results from standardized model wells indicate that, in sandstone-type uranium deposits, the absolute error of uranium content is within , and the relative error is within . These findings validate the feasibility of deriving the uranium–radium–radon balance coefficient without relying on core chemical analysis. Compared with the prompt neutron time spectrum logging method, the proposed approach significantly improves the logging speed while producing results that are essentially consistent with those of natural -ray total logging. It provides an efficient and accurate solution for uranium quantitative interpretation.
Magnetotelluric (MT) and magnetovariational (MV) sounding are two principal geophysical methods used to determine the electrical structure of the earth using natural electromagnetic signals. The complex relationship between the alternating electromagnetic fields can be defined by transfer functions, and their proper selection is crucial in a 3-D inversion. A synthetic case was studied to assess the capacity of these transfer functions to recover the electrical resistivity distribution of the subsurface and to evaluate the advantages and disadvantages of using the tipper vector W to complement the impedance tensor Z and the phase tensor Φ. The analysis started with two sensitivity tests to appraise the sensitivity of each type of transfer function, which is calculated for an oblique conductor model, showing that the resistivity perturbation of the same model will produce distinct perturbations to different transfer functions; the transfer function sensitivity is significantly different. A 3-D inversion utilizing the quasi-Newton method based on the L-BFGS formula was performed to invert different transfer functions and their combinations, along with quantifying their accuracy. The synthetic case study illustrates that a 3-D inversion of either the Z or Φ responses presents a superior ability to recover the subsurface electrical resistivity; joint inversions of the Z or Φ responses with the W responses possess superior imaging of the horizontal continuity of the conductive block. The appraisal of the 3-D inversion results of different transfer functions can facilitate assessing the advantages of different transfer functions and acquiring a more reasonable interpretation.