With the rapid development of multispectral detection technology, realizing the synergistic camouflage and thermal management of materials in multi-band has become a major challenge. In this paper, a multifunctional radiation-selective hierarchical metamaterial (RSHM) is designed to realize the modulation of optical properties in a wide spectral range through the delicate design of microstructures and nanostructures. In the atmospheric windows of 3–5 μm and 8–14 μm, the emissivity of the material is as low as 0.14 and 0.25, which can effectively suppress the radiation characteristics of the target in the infrared band, thus realizing efficient infrared stealth. Simultaneously, it exhibits high emissivity in the 2.5–3 μm (up to 0.80) and 5–8 μm (up to 0.98) bands, significantly improving thermal radiation efficiency and enabling active thermal management. Notably, RSHM achieves low reflectivity at 1.06 μm (0.13) and 1.55 μm (0.005) laser wavelengths, as well as in the 8–14 μm (0.06) band, substantially improving laser stealth performances. Additionally, it maintains high transmittance in the visible light range, ensuring excellent visual camouflage effects. Furthermore, the RSHM demonstrates exceptional incident angle and polarization stability, maintaining robust performances even under complex detection conditions. This design is easy to expand relative to other frequency bands of the electromagnetic spectrum and holds significant potential for applications in military camouflage, energy-efficient buildings, and optical devices.

Spectrally selective infrared absorbers play a pivotal role in enabling optoelectronic applications such as infrared detection, thermal imaging, and photothermal conversion. In this paper, a dual-band wide-spectrum infrared selective absorber based on a metal–dielectric multilayer structure is designed. Through optimized design, the absorptance of the absorber reaches the peak values of 0.87 and 1.0 in the target bands (3–5 μm and 8–14 μm), while maintaining a low absorptance of about 0.2 in the non-working bands of 5–8 μm, with excellent spectral selectivity. By analyzing the Poynting vector and loss distribution, the synergistic mechanism of the ultra-thin metal localized enhancement effect, impedance matching, and intrinsic absorption of the material is revealed. This structure exhibits good polarization-insensitive characteristics and angle robustness within a large incident angle range, showing strong adaptability to complex optical field environments. Moreover, the proposed planarized structure design is compatible with standard fabrication processes and has good scalability, which can be applied to other electromagnetic wave bands. This research provides new design ideas and technical solutions for advanced optoelectronic applications such as radiation cooling, infrared stealth, and thermal radiation regulation.