The photocatalytic activity of titanium dioxide (TiO₂) is largely hindered by its low photoresponse and quantum efficiency. TiO₂ modified by conjugated polymers (CPs) is considered a promising approach to enhance the visible light responsiveness of TiO₂. In this work, in order to investigate the effect of CP structural changes on the photocatalytic performance of TiO₂ under visible light, trimesoyl chloride–melamine polymers (TMPs) with different structural characteristics were created by varying the parameters of the polymerisation process of tricarbonyl chloride (TMC) and melamine (M). The TMPs were subsequently composited with TiO₂ to form complex materials (TMP–TiO₂) using an in situ hydrothermal technique. The photocatalytic activity of TMP–TiO₂ was evaluated by the degradation of rhodamine B (RhB). The results showed that the trend of the structure of the TMP with the reaction conditions was consistent with the visible light responsiveness of TMP–TiO₂, and TMP (1:1)–TiO₂ had the best photocatalytic activity and could degrade 96.1% of the RhB. In conclusion, our study provided new insights into the influence of the structural changes of TMPs on the photocatalytic activity of TMP–TiO₂ under visible light, and it improves our understanding of how conjugated polymers affect the photocatalytic activity of TiO₂ under visible light.

Nano-titanium dioxide (TiO₂) is currently the most widely studied photocatalyst. However, its rapid recombination of photogenerated carriers and narrow range of light absorption have limited its development. Crystal form regulation and polymer modification are important means for improving the photocatalytic activity of single-phase materials. In this paper, TiO₂ materials of different crystal forms were prepared by changing the synthesis conditions, and they were compounded with trimesoyl chloride–melamine polymers (TMPs) by the hydrothermal synthesis method. Then, their photocatalytic performance was evaluated by degrading methylene blue (MB) under visible light. The mechanisms of influence of TiO₂ crystal form on the photocatalytic activity of TiO₂-TMP were explored by combining characterization and theoretical calculation. The results showed that the TiO₂ crystal form, through interface interaction, the built-in electric field intensity of the heterojunction, and active sites, affected the interface charge separation and transfer, thereby influencing the photocatalytic activity of TiO₂-TMP. In the 4T-TMP photocatalytic system, the degradation rate of MB was the highest. These studies provide theoretical support for understanding the structure–property relationship of the interfacial electronic coupling between TiO₂ crystal forms and TMP, as well as for developing more efficient catalysts for pollutant degradation.