Phase change materials (PCMs) have significant potential for utilization due to their high energy storage density and excellent safety in energy storage. In this research, a flexible heat storage device using the stable supercooling of sodium acetate trihydrate composite is developed, enabling on-demand heat release through controlled solidification initiation. The solidification and heat release characteristics are investigated in experiments. The results indicate that the heat release characteristics of this heat storage device are closely linked to the crystallization process of the PCM. During the experiment, based on whether external intervention was needed for the solidification process, the PCM manifested two separate solidification modes—specifically, spontaneous self-solidification and triggered-solidification. Meanwhile, the heat release rates, temperature changes, and crystal morphologies were observed in the two solidification modes. Compared with spontaneous self-solidification, triggered-solidification achieved a higher peak surface temperature (53.6 °C vs. 46.2 °C) and reached 45 °C significantly faster (5 min vs. 15 min). Spontaneous self-solidification exhibited slower, uncontrollable heat release with dendritic crystals, while triggered-solidification provided rapid, controllable heat release with dense filamentous crystals. This controllable switching between modes offers key practical advantages, allowing the device to provide either rapid, high-power heat discharge or slower, sustained release as required by the application. According to the crystal solidification theory, the different supercooling degrees are the main reasons for the two solidification modes exhibiting different solidification characteristics. During solidification, the growth rate of SAT crystals exhibits substantial disparities across diverse experiments. In this research, the maximum axial growth rate is 2564 μm/s, and the maximum radial growth rate is 167 μm/s.

The growing share of intermittent renewable electricity has increased the need for long-duration storage in industrial energy systems. Meanwhile, many industrial processes still release recoverable low-grade waste heat. Introducing this heat into pumped thermal energy storage (PTES) can improve thermal integration, but industrial waste heat is often unsteady, and its temperature and mass flow fluctuations may disturb the charging process. This study investigates an air-based reverse Brayton PTES system assisted by an industrial hot-water waste heat stream of approximately 100 °C. A dynamic model was developed in Simulink/Simscape. The shaft speed is fixed at 3000 rpm, and a PID controller regulates the molten-salt flow rate to maintain the thermal storage temperature. The results show that increasing the waste heat temperature from 95 °C to 105 °C mainly changes the charging-side heat distribution. The waste heat utilization power increases from 36.0 MW to 37.9 MW, while the regenerator power decreases from 126.8 MW to 122.0 MW. The thermal storage power increases slightly from 117.0 MW to 119.0 MW, with the mechanical input fixed at 81.0 MW. The influence of waste heat temperature is concentrated near the low-temperature heat exchanger, regenerator, and turbine outlet. Under dynamic disturbances, faster temperature ramps increase short-term deviations, but the PID-based molten-salt flow regulation keeps the storage temperature close to 550 °C, indicating that the proposed control strategy can suppress moderate thermal disturbances during charging. When waste heat temperature and mass flow rate vary together, same-direction changes strengthen the disturbance, whereas opposite-direction changes partly offset it. These results clarify the disturbance propagation mechanism of fluctuating industrial waste heat in the PTES charging loop and provide a basis for the dynamic design and temperature-control strategy of waste-heat-assisted PTES systems.