Graphene is one of the most promising materials in nanotechnology. From a theoretical point of view, it provides the ultimate two-dimensional model of a catalytic support. Its unique physical, chemical and mechanical properties are outstanding, and could allow the preparation of composite-materials with unprecedented characteristics. Even though the use of a single graphene sheet as a catalytic support has not yet been reported, some promising results have already been obtained with few-layer graphene. In this review, we will briefly discuss the most relevant synthetic routes to obtain graphene. Then, we will focus our attention on the properties and characterization techniques of graphene that are of relevance to catalysis, with emphasis on adsorption. After presenting an overview of the most common and effective preparation methods, we will discuss the catalytic application of graphene and graphene-based composites, with particular attention on energy conversion and photocatalysis.

"We heartily recommend this book to all readers who wish to gain a better understanding of nanostructured carbon materials surface properties and used in catalysis." An-Hui Lu, ChemCatChem There is great interest in using nanostructured carbon materials in catalysis, either as supports for immobilizing active species or as metal-free catalysts due to their unique structural, thermal, chemical, electronic and mechanical properties, and tailorable surface chemistry. This book looks at the structure and properties of different doped and undoped nanocarbons including graphene; fullerenes; nanodiamonds; carbon nanotubes and nanofibers; their synthesis and modification to produce catalysts. Special attention is paid to adsorption, as it impacts the application of these materials in various industrially relevant catalytic reactions discussed herein, in addition to photocatalysis and electrocatalysis. Written by leading experts in the area, this is the first book to provide a comprehensive view of the subject for the catalysis community.