Residential and agricultural buildings must prioritize environmental sustainability, employing locally sourced, bio/geologically sustainable materials, and reversible construction methods. Hence, adobe construction and earth-based building methods are experiencing a comeback. This article describes the hygrothermal performances of a real scale agricultural building prototype, in real field conditions, built and designed to be energy-efficient, environmentally friendly, and well-suited for the hot, dry climates typical of the Mediterranean region during summer. The building prototype is a small modular two room construction, one room based on wood (for control purpose) and the other one on raw earth. The experimental set up highlights the passive cooling and humidity regulation potential provided by raw earth and adobe brick technology in agricultural buildings used for fruit and vegetable storage. Such passive cooling alternatives in the Mediterranean climate could reduce the need for energy-intensive and environmentally impactful cold storage rooms.