The end-notched flexure (ENF) test calculates the value of mode II fracture energy in adhesive bonding between the substrates of same nature. Traditional methods of calculating fracture energy in the ENF test are not suitable in cases where the thickness of the adhesive is non-negligible compared with adherent thicknesses. To address this issue, a specific methodology for calculating mode II fracture energy has been proposed in this paper. To illustrate the applicability of the proposed method, the fracture energy was calculated by the ENF test for adhesive bonds between aluminium and a composite material, which considered two different types of adhesive (epoxy and polyurethane) and various surface treatments. The proposed calculation model provides higher values of fracture energy than those obtained from the simplified models that consider the adhesive thickness to be zero, supporting the conclusion that the calculation of mode II fracture energy for adhesives with non-negligible thickness relative to their adherents should be based on mathematical models, such as the method proposed in this paper, that incorporate the influence of this thickness.

In order to obtain the advantages of structural adhesives, a specific design of the adhesive joint is required, enhancing its performance and restricting its limitations. One of the most relevant geometrical patterns is the surface finish of the substrates as it decisively influences the mechanical properties of the joint and has a clear economical impact on the large series manufacturing processes. The contact of the adhesive with the metal (that in some cases is an activator of polymerization) and the presence of air bubbles trapped in the roughness (if abundant and larger than the polymer molecules) can lead to the appearance of cracks, causing the fracture of the adhesive layer or an adhesive failure. The objective of the present report is to analyse the influence of the roughness (as a pre-treatment before bonding) on the mechanical performance of the joint and, by means of the application of the “Value Analysis” technique, propose the surface finish that combines best both mechanical performance and suitability to the manufacturing process. The obtained results provide excellent expectations to achieve high performance of the adhesive joint with more economical and environmentally friendly surface finishes than rough machining (less waste of material, less costs in tooling and machinery, lower manufacturing times, etc.) and, therefore, enabling a better and wider use of adhesives in the industrial manufacturing processes.

The adhesives used for applications in marine environments are subject to particular chemical conditions, which are mainly characterised by an elevated chlorine ion content and intermittent wetting/drying cycles, among others. These conditions can limit the use of adhesives due to the degradation processes that they experience. In this work, the chemical degradation of two different polymers, polyurethane and vinylester, was studied in natural seawater under immersion for different periods of time. The diffusion coefficients and concentration profiles of water throughout the thickness of the adhesives were obtained. Microstructural changes in the polymer due to the action of water were observed by SEM, and the chemical degradation of the polymer was monitored with the Fourier transform infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC). The degradation of the mechanical properties of the adhesive was determined by creep tests with Mixed Cantilever Beam (MCB) specimens at different temperatures. After 180 days of immersion of the specimens, it was concluded that theJ-integral value (depending on the strain) implies a loss of stiffness of 51% and a decrease in the failure load of 59% for the adhesive tested.

Means of transport should be able to fulfil their main function safely and comfortably for travellers and drivers. The effects of vibrations on ride comfort are in the frequency range of 0.5 to 80 Hz and can be analysed using the UNE-2631 standard. This type of analysis has been conducted for several means of transport (bicycles, motorcycles, cars, trucks, etc.), but the literature on e-scooter comfort is very scarce. Existing research describes methodologies, simulation models, and a few measurements related to e-scooter comfort. This paper presents, for the first time, a comfort analysis using an Arduino-based data acquisition system at a sampling frequency of 200 Hz (higher than that in previous studies). Acceleration and speed measurements were obtained by sensorising an e-scooter with inflated wheels without any additional damping systems, which is one of the commonly used e-scooter types. In this study, the comfort for two different speeds (20 and 28 km/h), two types of pavements (pavers and asphalt), and two drivers with different weights was investigated. The results indicate the lowest comfort values for higher velocities and paver pavement. Furthermore, the comfort values were extremely low for all scenarios. In addition, the results demonstrate the necessity of using a sampling rate of at least 80 Hz for this e-scooter model.

Vinyl ester (VE) resins are widely used as thermoset adhesives in structural joints and composites, but complete curing under environmental conditions is not produced. The existing literature dealing with the effect of post-curing on the structure, viscoelastic, mechanical, and adhesion properties of VE resin is scarce. Therefore, in this study, VE resin was subjected to different post-curing temperatures (50–140 °C) for one hour, and the changes in structure and properties were assessed. The degree of cross-linking of the VE resin depended on the post-curing temperature and cure started to be completed above 100 °C, a temperature close to the glass transition temperature (115 °C) of the completely cross-linked polymer. Furthermore, gel formation in VE resin was evidenced for post-curing temperature below 100 °C. In order to fully cross-link the VE resin, post-curing at 140 °C for one hour was necessary, and it was evidenced by an increase in the glass transition temperature and in the mechanical properties; an increase in adhesion to cold rolled steel was obtained although the shear strength was lower than in the joint produced with the non-post-cured VE resin.