A fully physical retrieval scheme for land surface emissivity spectra is presented, which applies to high spectral resolution infrared observations from satellite sensors. The surface emissivity spectrum is represented with a suitably truncated Principal Component Analysis (PCA) transform and PCA scores are simultaneously retrieved with surface temperature and atmospheric parameters. The retrieval methodology has been developed within the general framework of Optimal Estimation and, in this context, is the first physical scheme based on a PCA representation of the emissivity spectrum. The scheme has been applied to IASI (Infrared Atmospheric Sounder Interferometer) and the retrieved emissivities have been validated with in situ observations acquired during a field experiment carried out in 2017 at Gobabeb (Namib desert) validation station. It has been found that the retrieved emissivity spectra are independent of background information and in good agreement with in situ observations.

The monitoring of the Land Surface Temperature (LST) by remote sensing in urban areas is of great interest to study the Surface Urban Heat Island (SUHI) effect. Thus, it is one of the goals of the future spaceborne mission TRISHNA, which will carry a thermal radiometer onboard with four bands at a 60-m spatial resolution, acquiring daytime and nighttime. In this study, TRISHNA-like data are simulated from Airborne Hyperspectral Scanner (AHS) data over the Madrid urban area at 4-m resolution. To retrieve the LST, the Temperature and Emissivity Separation (TES) algorithm is applied with four spectral bands considering two main original approaches compared with the classical TES algorithm. First, calibration and validation datasets with a large number of artificial materials are considered (called urban-oriented database), contrary to most of the previous studies that do not use a large number of artificial material spectra during the calibration step, thus impacting the LST retrieval over these materials. This approach produces one TES algorithm with one empirical relationship, called 1MMD TES. Second, two empirical relationships are used, one for the artificial materials and the other for the natural ones. These relationships are defined thanks to two calibration datasets (artificial-surface-oriented database and natural-surface-oriented database, respectively), one containing mainly artificial materials and the other mainly natural ones. Finally, in order to use two empirical relationships, a ground cover classification map is given to the TES algorithm to separate artificial pixels from natural ones. This approach produces one material-oriented TES algorithm with two empirical relationships, called 2MMD TES. In order to perform a complete comparison of these two addenda in the TES algorithm and their impact on the LST retrieval, both AHS and TRISHNA spatial resolutions are studied, i.e., 4-m and 60-m resolutions, respectively. Relative to the calibration of the TES algorithm, we conclude that (1) the urban-oriented database is more representative of the urban areas than previous databases from the state-of-the-art, and (2) using two databases (artificial-surface-oriented and natural-surface-oriented) instead of one prevents the overestimation of the LST over natural materials and the underestimation over artificial ones. Thus, for both studied spatial resolutions (AHS and TRISHNA), we find that the 2MMD TES outperforms the 1MMD TES. This difference is especially important for artificial materials, corroborating the above conclusion. Furthermore, the comparison with ground measurements shows that, on 4-m spatial resolution images, the 2MMD TES outperforms both the 1MMD TES and the TES from the state-of-the-art used in this study. Finally, we conclude that the 2MMD TES method, with only four spectral bands, better retrieves the LST over artificial and natural materials and that the future TRISHNA sensor is suited for the monitoring of the LST over urban areas and the SUHI effect.

In this paper, we focus on airborne hyperspectral imaging methodology to characterize particulate matter (PM) near industrial emission sources. Two short-term intensive campaigns were carried out in the vicinity of a refinery in the south of France, in September 2015 and February 2016. Different protocols of in situ PM measurements were performed, at stack measurements (flow rate and offline chemical analysis) and online measurement at the refinery border (size distribution, concentration, and chemistry of aerosols). A multitemporal methodology to retrieve aerosol type, to map the aerosol concentration, and to quantify mass flow rate from airborne hyperspectral data is described in this paper. This method applied to the refinery detected plume from the main stack yields a black carbon to sulfate ratio of 10/90 in mass inside the plume, with an average size distribution smaller than 100 nm. These results are in a good agreement with the online analysis of aerosols at the refinery border. The resulting quantitative map with a metric spatial resolution leads to an estimated flow rate of about 1 g/s and is in a good agreement with in situ stack measurements and modeling.

Timely processing of observations from multi-spectral imagers, such as SEVIRI (Spinning Enhanced Visible and Infrared Imager), largely depends on fast radiative transfer calculations. This paper mostly concerns the development and implementation of a new forward model for SEVIRI to be applied to real time processing of infrared radiances. The new radiative transfer model improves computational time by a factor of ≈7 compared to the previous versions and makes it possible to process SEVIRI data at nearly real time. The new forward model has been applied for the retrieval of surface parameters. Although the scheme can be applied for the simultaneous retrieval of temperature and emissivity, the paper mostly focuses on emissivity. The inverse scheme relies on a Kalman filter approach, which allows us to exploit a sequential processing of SEVIRI observations. Based on the new forward model, the paper also presents a validation retrieval performed with in situ observations acquired during a field experiment carried out in 2017 at Gobabeb (Namib desert) validation station. Furthermore, a comparison with IASI (Infrared Atmospheric Sounder Interferometer) emissivity retrievals has been performed as well. It has been found that the retrieved emissivities are in good agreement with each other and with in situ observations, i.e., average differences are generally well below 0.01.

Information on spectral emissivity (SE) is vital when retrieving and evaluating land surface temperature (LST) estimates from remotely sensed observations. SE measurements often come from spectral libraries based upon laboratory spectroscopic measurements, with uncertainties typically derived from repeated measurements. To go further, we organised a “round-robin” inter-comparison exercise involving SE measurements of three samples collected at seven different international laboratories. The samples were distilled water, which has a uniformly high spectral emissivity, and two artificial samples (aluminium and gold sheets laminated in polyethylene), with variable emissivities and largely specular and Lambertian characteristics. Large differences were observed between some measurements, with standard deviations over 2.5–14 μm of 0.092, 0.054 and 0.028 emissivity units (15.98%, 7.56% and 2.92%) for the laminated aluminium sheet, laminated gold sheet and distilled water respectively. Wavelength shifts of up to 0.09 μm were evident between spectra from different laboratories for the specular sample, attributed to system design interacting with the angular behaviour of emissivity. We quantified the impact of these SE differences on satellite LST estimation and found that emissivity differences resulted in LSTs differing by at least 3.5 K for each artificial sample and by more than 2.5 K for the distilled water. Our findings suggest that variations between SE measurements derived via laboratory setups may be larger than previously assumed and provide a greater contribution to LST uncertainty than thought. The study highlights the need for the infrared spectroscopy community to work towards standardized and interlaboratory comparable results.

Timely processing of observations from hyper-spectral imagers, such as SEVIRI (Spinning Enhanced Visible and Infrared Imager), largely depends on fast radiative transfer calculations. This paper mostly concerns the development and implementation of a new forward model for SEVIRI to be applied to real time processing of infrared radiances for the physical retrieval of surface temperature and emissivity. The new radiative transfer model improves computational time by a factor of ≈ 7 compared to the previous versions and makes it possible to process SEVIRI data at nearly real time. The new forward model has been applied for the simultaneous retrieval of surface temperature and emissivity in three infrared channels (8.7, 10.8, 12 μm). The inverse scheme relies on a Kalman filter approach, which allows us to exploit a sequential processing of SEVIRI observations. Based on the new forward model, the paper also presents a validation retrieval performed with in situ observations acquired during a field experiment carried out in 2017 at Gobabeb (Namib desert) validation station. Furthermore, a comparison with IASI (Infrared Atmospheric Sounder Interferometer) emissivity retrievals has been performed as well. It has been found that the retrieved emissivities are in good agreement with each other and with in situ observations, i.e. average differences are generally well below 0.01.