In silicon–carbon (Si-C) anode materials fabricated via chemical vapor deposition (CVD), the pore size distribution of porous carbon is a critical parameter that strongly affects the overall electrochemical performance. In this study, biomass-derived hard carbon was employed as the precursor, and porous carbon materials with distinct pore size characteristics were prepared via fluidized bed porosimetry after carbonization at different temperatures. Based on these porous carbon substrates, three types of Si-C anodes corresponding to low-, medium-, and high-temperature treatments were synthesized through a combination of SiH₄ deposition and carbon coating processes. Electrochemical evaluation demonstrated that all three Si-C anodes exhibited favorable electrochemical performance and suppressed volume expansion. Among them, the Si-C anode prepared at a medium temperature of 1100 °C, denoted as NT-P-SC, delivered the most balanced performance, achieving an initial coulombic efficiency of 94.47% together with excellent rate capability. Furthermore, when Si-C anodes derived from different porous carbon matrices were blended with graphite to achieve a composite capacity of 500 mAh/g and evaluated in full-cell configurations, the NT-P-SC silicon-based composite exhibited superior cycling stability. The composite delivered an initial discharge capacity of 3.53 mAh and maintained a capacity of 2.74 mAh after 1628 cycles, corresponding to a capacity retention of 77.62%. The improved electrochemical performance of the Si-C anode is primarily attributed to the optimized pore structure of the porous carbon matrix synergistically combined with the carbon coating process.

An industrial submicron-sized Fe₂O₃ with no special shape was decorated by a multi-layer coating of oxygen-deficient TiO_2−x and conducting polymer PEDOT (poly 3,4-ethylenedioxythiophene). A facile sol–gel method followed by an EDOT polymerization process was adopted to synthesize the hierarchical coating composite. The microstructure and phase composition were characterized using an X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). In particular, the existence state of PEDOT was determined using Fourier transform infrared (FT-IR) and a thermogravimetric (TG) analysis. The characterization results indicated the dual phase was well-coated on the Fe₂O₃ and its thickness was nano scale. Electrochemical characterization indicated that the multi-layer coating was helpful for significantly enhancing the cycle stability of the Fe₂O₃, and its electrochemical performance was even better than that of the single-layer coating samples. The synergistic effects of the ceramic phase and conducting polymer were demonstrated to be useful for improving electrochemical properties. The obtained FTP-24 sample exhibited a specific discharge capacity of 588.9 mAh/g after 360 cycles at a current density of 100 mA/g, which effectively improved the intrinsic cycling performance of the Fe₂O₃, with a corresponding discharge capacity of 50 mAh/g after 30 cycles.