Machine learning (ML) algorithms have shown great performance in geological remote sensing applications. The study area of this work was the Fregeneda–Almendra region (Spain–Portugal) where the support vector machine (SVM) was employed. Lithium (Li)-pegmatite exploration using satellite data presents some challenges since pegmatites are, by nature, small, narrow bodies. Consequently, the following objectives were defined: (i) train several SVM’s on Sentinel-2 images with different parameters to find the optimal model; (ii) assess the impact of imbalanced data; (iii) develop a successful methodological approach to delineate target areas for Li-exploration. Parameter optimization and model evaluation was accomplished by a two-staged grid-search with cross-validation. Several new methodological advances were proposed, including a region of interest (ROI)-based splitting strategy to create the training and test subsets, a semi-automatization of the classification process, and the application of a more innovative and adequate metric score to choose the best model. The proposed methodology obtained good results, identifying known Li-pegmatite occurrences as well as other target areas for Li-exploration. Also, the results showed that the class imbalance had a negative impact on the SVM performance since known Li-pegmatite occurrences were not identified. The potentials and limitations of the methodology proposed are highlighted and its applicability to other case studies is discussed.

Optical and thermal remote sensing data have been an important tool in geological exploration for certain deposit types. However, the present economic and technological advances demand the adaptation of the remote sensing data and image processing techniques to the exploration of other raw materials like lithium (Li). A bibliometric analysis, using a systematic review approach, was made to understand the recent interest in the application of remote sensing methods in Li exploration. A review of the application studies and developments in this field was also made. Throughout the paper, the addressed topics include: (i) achievements made in Li exploration using remote sensing methods; (ii) the main weaknesses of the approaches; (iii) how to overcome these difficulties; and (iv) the expected research perspectives. We expect that the number of studies concerning this topic will increase in the near future and that remote sensing will become an integrated and fundamental tool in Li exploration.

As an important source of lithium and rare earth elements (REE) and other critical elements, pegmatites are of great strategic economic interest for present and future technological development. Identifying new pegmatite deposits is a strategy adopted by the European Union (EU) to decrease its import dependence on non-European countries for these raw materials. It is in this context that the GREENPEG project was established, an EU project whose main objective is to identify new deposits of pegmatites in Europe in an environmentally friendly way. Remote sensing is a non-contact exploration tool that allows for identifying areas of interest for exploration at the early stage of exploration campaigns. Several RS methods have been developed to identify Li-Cs-Ta (LCT) pegmatites, but in this study, a new methodology was developed to detect Nb-Y-F (NYF) pegmatites in the Tysfjord area in Norway. This methodology is based on spectral analysis to select bands of the Sentinel 2 satellite and adapt RS methods, such as Band Ratios and Principal Component Analysis (PCA), to be used as input in the Random Forest (RF) and other tree-based ensemble algorithms to improve the classification accuracy. The results obtained are encouraging, and the algorithm was able to successfully identify the pegmatite areas already known and new locations of interest for exploration were also defined.

Reflectance spectroscopy has been used to identify several deposit types. However, applications concerning lithium (Li)-pegmatites are still scarce. Reflectance spectroscopic studies complemented by microscopic and geochemical studies were employed in the Fregeneda–Almendra (Spain–Portugal) pegmatite field to analyze the spectral behavior of Li-minerals and field lithologies. The spectral similarity of the target class (Li-pegmatites) with other elements was also evaluated. Lepidolite was discriminated from other white micas and the remaining Li-minerals. No diagnostic feature of petalite and spodumene was identified, since their spectral curves are dominated by clays. Their presence was corroborated (by complementary techniques) in petalite relics and completely replaced crystals, although the clay-related absorption depths decrease with Li content. This implies that clays can be used as pathfinders only in areas where argillic alteration is not prevalent. All sampled lithologies present similar water and/or hydroxide features. The overall mineral assemblage is very distinct, with lepidolite, cookeite, and orthoclase exclusively identified in Li-pegmatite (being these minerals crucial targets for Li-pegmatite discrimination in real-life applications), while chlorite and biotite can occur in the remaining lithologies. Satellite data can be used to discriminate Li-pegmatites due to distinct reflectance magnitude and mineral assemblages, higher absorptions depths, and distinct Al–OH wavelength position. The potential use of multi- and hyperspectral data was evaluated; the main limitations and advantages were discussed. These new insights on the spectral behavior of Li-minerals and pegmatites may aid in new Li-pegmatite discoveries around the world.

The growing importance and demand of lithium (Li) for industrial applications, in particular rechargeable Li-ion batteries, have led to a significant increase in exploration efforts for Li-bearing minerals. To ensure and expand a stable Li supply to the global economy, extensive research and exploration are necessary. Artificial neural networks (ANNs) provide powerful tools for exploration target identification. They can be cost-effectively applied in various geological settings. This article presents an integrated approach of Li exploration targeting using ANNs for data interpretation. Based on medium resolution geological maps (1:50,000) and stream sediment geochemical data (1 sample per 0.25 km²), the Li potential was calculated for an area of approximately 1200 km² in the surroundings of Bajoca Mine (Northeast Portugal). Extensive knowledge about geological processes leading to Li mineralisation (such as weathering conditions and diverse Li minerals) proved to be a determining factor in the exploration model. Furthermore, Sentinel-2 satellite imagery was used in a separate ANN model to identify potential Li mine sites exposed on the ground surface by analysing the spectral signature of surface reflectance in well-known Li locations. Finally, the results were combined to design a final map of predicted Li mineralisation occurrences in the study area. The proposed approach reveals how remote sensing data in combination with geological and geochemical data can be used for delineating and ranking exploration targets of almost any deposit type.