Calcium alginate (CaAlg) is a kind of biodegradable and eco-friendly functional material, and CaAlg/reduced graphene oxide (rGO) composites are expected to be applied as new textile, heat-generating, and flame-retardant materials. In this paper, the CaAlg/rGO composites were prepared by a sol-gel method and their morphological and thermal properties were studied. The results showed that the introduction of rGO can efficiently improve the thermal stability of CaAlg. Further study showed that rGO increased the carbon formation rate by 4.1%, indicating that the thermal stability was improved by the promotion of carbon formation. Moreover, the weight loss rate of the composites was faster at 180–200 °C than that of CaAlg, after which the rate was less comparatively, suggesting the better thermal stability of the composite. This maybe because the high heat transfer efficiency of rGO allowed the material to reach the temperature of the thermal decomposition of the glycan molecule chain within a short time, and then promoted carbon formation. The thermal cracking mechanism of the composites is proposed based on the experimental data.

Detection of mercury (Hg²⁺) and sulfide (S²⁻), universal and well-known toxic ions, is crucial in monitoring several diseases. How to design and fabricate the high-performance sensor for simultaneously and accurately detecting the Hg²⁺ and S²⁻ is critical. Herein, we proposed a novel and convenient strategy for optical detection of Hg²⁺ and S²⁻ by employing a carboxymethyl cellulose sodium/silver nanoparticle (CMS/AgNPs) colloidal solution, in which AgNPs were used as monitor for Hg²⁺ and S²⁻, and the CMS was utilized as both the stabilizer and the hydrophilic substrate for AgNPs. Well-identifiable peaks for Hg²⁺ and S^2– were obtained in water based on UV–VIS absorption spectra, the absorbance intensity and/or position of nano-silver vary with the addition of Hg²⁺ cation and S^2– anion, accompanying with color change. Impressively, the optimal AgNPs anchored CMS exhibited a high sensitivity and selectivity toward Hg²⁺ and S²⁻, the change in absorbance was linear with the concentration of Hg²⁺ (0–50 μM) and S²⁻ (15–70 μM), and the lowest limits of detection (LOD) were 1.8 × 10⁻⁸ M and 2.4 × 10⁻⁷ M, respectively. More importantly, owing to the superior properties in testing Hg²⁺ and S²⁻, the fabricated sensor was successfully applied for detection of target ions in lake and tap water samples. All these good results implied that the designed strategy and as-designed samples is promising in detecting cation (Hg²⁺) and anion (S²⁻) ions and open up new opportunities for selecting other kinds of ions.