Authigenic grain-coating chlorite is widely distributed in the clastic rocks of many sedimentary basins around the world. These iron minerals were mainly derived from flocculent precipitates formed when rivers flow into the ocean, especially in deltaic environments with high hydrodynamic conditions. At the same time, sandstone sequences with grain-coating chlorites also tend to have relatively high glauconite and pyrite content. EPMA composition analysis shows that glauconites with “high Al and low Fe” content indicate slightly to semi-saline marine environments with weak alkaline and weakly reducing conditions. By analyzing the chlorite-containing sandstone bodies of the southern Sichuan Xujiahe Formation, this study found that chlorite was mainly distributed in sedimentary microfacies, including underwater distributary channels, distributary channels, shallow lake sandstone dams, and mouth bars. Chlorite had a tendency to form in the upper parts of sandstone bodies with signs of increased base level, representing the influence of marine (lacustrine) transgression. This is believed to be influenced by megamonsoons in the Middle and Upper Yangtze Region during the Late Triassic Epoch. During periods of abundant precipitation, river discharges increased and more Fe particulates flowed into the ocean (lake). In the meantime, increases or decreases in lake level were only affected by precipitation for short periods of time. The sedimentary environment shifted from weakly oxidizing to weak alkaline, weakly reducing conditions as sea level increased, and Fe-rich minerals as authigenic chlorite and glauconite began to form and deposit.

The Longtan Formation of the Upper Permian in the Sichuan Basin has become a significant target for shale gas exploration in recent years. Multiple methods, including outcrop observations, thin sections, total organic matter content, X-ray diffraction and scanning electron microscopy were used to investigate the mineralogy, shale lithofacies assemblages and their relationships with the deposition environment. The mineral composition of the Longtan Formation has strong mineral heterogeneity. The TOC values of the Longtan Formation have a wide distribution range from 0.07% to 74.67% with an average value of 5.73%. Four types of shale lithofacies assemblages of the Longtan Formation could be distinguished, as clayey mudstone (CLS), carbonaceous shale (CAS), siliceous shale (SS) and mixed shale (MS) on the basis of mineral compositions. The TOC values of various types of shale lithofacies assemblages in the Longtan Formation varied widely. The shore swamp of the Longtan Formation is most influenced by the terrestrial input and mainly develops CLS and MS. The tidal flat is influenced by the terrestrial input and can also deposit carbonate minerals, developing CLS, CAS and MS. The shallow water melanged accumulation shelf develops CAS and MS, dominated by clay and carbonate minerals. The deep water miscible shelf develops CLS and SS, whose mineral composition is similar to that of the shore swamp, but the quartz minerals are mainly formed by chemical and biological reactions, which are related to the Permian global chert event. The depositional environment of the Longtan Formation controls the shale mineral assemblage of the Longtan Formation and also influences the TOC content.