Nanoparticles play a significant role in various fields ranging from electronics to composite materials development. Among them, metal nanoparticles have attracted much attention in recent decades due to their high surface area, selectivity, tunable morphologies, and remarkable catalytic activity. In this review, we discuss various possibilities for the synthesis of different metal nanoparticles; specifically, we address some of the green synthesis approaches. In the second part of the paper, we review the catalytic performance of the most commonly used metal nanoparticles and we explore a few roadblocks to the commercialization of the developed metal nanoparticles as efficient catalysts.
Leather industry produces huge quantities of bio-waste that can be used as raw material for the bulk synthesis of carbonaceous materials. Here we report the synthesis of multifunctional carbon nanostructures from pristine collagen wastes by a simple high temperature treatment. Our studies reveal that the nanocarbons derived from the bio-waste have a partially graphitized structure with onion-like morphology and are naturally doped with nitrogen and oxygen, resulting in multifunctional properties. This synthetic route from bio-waste raw material provides a cost-effective alternative to existing chemical vapor deposition methods for the synthesis of functional nanocarbon materials and presents a sustainable approach to tailor nanocarbons for applications such as battery electrodes.
The energy crisis is one of the most serious issue that we confront today. Among different strategies to gain access to reliable fuel, the production of hydrogen fuel through the water-splitting reaction has emerged as the most viable alternative. Specifically, the studies on defect-rich TiO2 materials have been proved that it can perform as an efficient catalyst for electrocatalytic and photocatalytic water-splitting reactions. In this invited review, we have included a general and critical discussion on the background of titanium sub-oxides structure, defect chemistries and the consequent disorder arising in defect-rich Titania and their applications towards water-splitting reactions. We have particularly emphasized the origin of the catalytic activity in Titania-based material and its effects on the structural, optical and electronic behavior. This review article also summarizes studies on challenging issues on defect-rich Titania and new possible directions for the development of an efficient catalyst with improved catalytic performance.