Bulk metallic glasses (BMGs) are promising for multifunctional and structural application in different industries. However, the limited size of BMGs hinders their further application. The welding of BMGs has shown the possibility of getting rid of the casting size limitation. The heat-affected zone (HAZ) and fusion zone (FZ) often undergo severe crystallization during the welding process. It is still unclear whether the crystallization occurs during the heating process or the cooling process. To figure out the crystallization mechanisms of Zr-based BMGs during the electron beam welding process, the Zr-based BMGs with the composition of Zr_41.2Ti_13.8Cu_12.5Ni₁₀Be_22.5 were remelted by electron beam. The microstructures of the HAZ and the remelting zone (RZ) were analyzed. The thermal field of the electron beam welding was obtained by the finite element method (FEM). The critical conditions for crystallization during the heating and cooling processes were obtained by differential scanning calorimetry (DSC) and the Kissinger equation. The results show that the Zr_41.2Ti_13.8Cu_12.5Ni₁₀Be_22.5 in the HAZ undergoes severe crystallization, while the Zr_41.2Ti_13.8Cu_12.5Ni₁₀Be_22.5 in RZ keeps amorphous state after the remelting process. The low cooling rate in the HAZ is responsible for its crystallization.

High nitrogen steel (HNS) has an excellent tensile strength and impact property due to the solid solution strengthening of nitrogen, which provides a good application prospect in many fields. Fusion welding is one of the main processing methods of HNS, but the process is prone to spatters, serious nitrogen losses, N₂ porosities, and poor performances of joints, resulting in the failure of large-scale engineering applications of HNS. In this work, the development of HNS welding is reviewed, and the problems including the droplet transfer instability, N₂ porosities, nitrogen losses and poor mechanical properties due to high nitrogen content are discussed. According to previous welding experiences, the adoption of a welding method with a low heat input is proposed, which utilizes powders instead of wires, optimizes compositions in the shielding gas and feeding materials in order to solve the above problems, and improves the mechanical properties of the weld.