Negative Poisson’s ratio (NPR) reinforcement offers a novel solution to the usual trade-off between strength gains and ductility loss. Incorporating NPR into ultra-high-performance concrete (UHPC) effectively overcomes the ductility limitations of structural elements. However, the interfacial bonding between NPR reinforcement and UHPC is not sufficiently studied, especially its patterns and mechanisms, impeding the application of the materials. In this paper, the effects of nine design parameters (rebar type, prestrain, etc.) on the bond performance of NPR-UHPC through eccentric pull-out tests are investigated, and a quantitative discriminative indicator K_c for NPR-UHPC bond failure modes is established. The results showed that when K_c ≤ 4.3, 4.3 < K_c ≤ 5.64, and K_c ≥ 5.6, the NPR-UHPC specimens undergo splitting failure, splitting–pull-out failure, and pull-out failure, respectively. In terms of bonding with UHPC, the NPR bars outperform the HRB400 bars, and the HRB400 bars outperform the helical grooved (HG) bars. For the NPR bars, prestrain levels of 5.5%, 9.5%, and 22.0% decrease τ_u by 5.07%, 7.79%, and 17.01% and s_u by 7.00%, 15.88%, and 30.54%, respectively. Bond performance deteriorated with increasing rib spacing and decreasing rib height. Based on the test results, an artificial neural network (ANN) model is developed to accurately predict the critical embedded length l_cd and ultimate embedded length l_ud between NPR bars and UHPC. Moreover, the MAPE of the ANN model is only 53.9% of that of the regression model, while the RMSE is just 62.0%.

Ordinary steel slag serves as a supplementary cementitious material (SCMs) to enhance the resource efficiency of industrial waste and contribute to decarbonization and economic benefits. However, there are significant differences in the composition and properties between hot–stuffy steel slag and ordinary steel slag, and there has been little research focusing on hot–stuffy steel slag as an SCM. Herein, we investigated the application of hot–stuffy steel slag, coal bottom ash, slag powder, desulfurization gypsum, and cement as raw materials for developing new green, low-carbon, and economical cementitious materials. When the hot–stuffy steel slag content was 20%, the compressive and flexural strengths of the cementitious material at 28 days reached as high as 64.5 MPa and 11.3 MPa, respectively. Even when the hot–stuffy steel slag content is increased to 50%, the compressive and flexural strengths at 28 days remain 58.2 MPa and 6.1 MPa, respectively. Furthermore, an X-ray diffractometer (XRD) and scanning electron microscopy (SEM) show that the hydration products generated by the new low-carbon cementitious materials (LCM) are mainly C-(A)-S-H gels. Mercury intrusion porosimetry (MIP) indicates that when the hot–stuffy steel slag content is 20%, the total porosity (18.85%) of the LCM is the lowest, suggesting that the lower the porosity, the better the strength. Notably, the heavy metal ions released by hot–stuffy steel slag-based cementitious materials were far below hygienic standards for drinking water, confirming their ability to fix heavy metal ions. This work provides an excellent model and application prospect for the utilization of hot–stuffy steel slag in non-structural engineering projects such as river engineering, marine engineering, and road engineering, enabling the achievement of both low-carbon and economic objectives.