The increasing demand for wearable optoelectronics in biomedicine, prosthetics, and soft robotics calls for innovative and transformative technologies that permit facile fabrication of compact and flexible photodetectors with high performance. Herein, by developing a single‐step selective laser writing strategy that can finely tailor material properties through incident photon density control and lead to the formation of hierarchical hybrid nanocomposites, e.g., reduced graphene oxide (rGO)–zinc oxide (ZnO), a highly flexible and all rGO–ZnO hybrid‐based photodetector is successfully constructed. The device features 3D ultraporous hybrid films with high photoresponsivity as the active detection layer, and hybrid nanoflakes with superior electrical conductivity as interdigitated electrodes. Benefitting from enhanced photocarrier generation because of the ultraporous film morphology, efficient separation of electron–hole pairs at rGO–ZnO heterojunctions, and fast electron transport by highly conductive rGO nanosheets, the photodetector exhibits high, linear, and reproducible responsivities to a wide range of ultraviolet (UV) intensities. Furthermore, the excellent mechanical flexibility and robustness enable the photodetector to be conformally attached to skin, thus intimately monitoring the exposure dosage of human body to UV light for skin disease prevention. This study advances the fabrication of flexible optoelectronic devices with reduced complexity, facilitating the integration of wearable optoelectronics and epidermal systems.

Lithium-sulfur (Li-S) batteries as power supply systems possessing a theoretical energy density of as high as 2600 Wh kg ⁻¹ are considered promising alternatives toward the currently used lithium-ion batteries (LIBs). However, the insulation characteristic and huge volume change of sulfur, the generation of dissolvable lithium polysulfides (LiPSs) during charge/discharge, and the uncontrollable dendrite formation of Li metal anodes render Li-S batteries serious cycling issues with rapid capacity decay. To address these challenges, extensive efforts are devoted to designing cathode/anode hosts and/or modifying separators by incorporating functional materials with the features of improved conductivity, lithiophilic, physical/chemical capture ability toward LiPSs, and/or efficient catalytic conversion of LiPSs. Among all candidates, molybdenum-based (Mo-based) materials are highly preferred for their tunable crystal structure, adjustable composition, variable valence of Mo centers, and strong interactions with soluble LiPSs. Herein, the latest advances in design and application of Mo-based materials for Li-S batteries are comprehensively reviewed, covering molybdenum oxides, molybdenum dichalcogenides, molybdenum nitrides, molybdenum carbides, molybdenum phosphides, and molybdenum metal. In the end, the existing challenges in this research field are elaborately discussed.

Non‐invasive human‐machine interactions (HMIs) are expected to be promoted by epidermal tactile receptive devices that can accurately perceive human activities. In reality, however, the HMI efficiency is limited by the unsatisfactory perception capability of mechanosensors and the complicated techniques for device fabrication and integration. Herein, a paradigm is presented for high‐throughput fabrication of multimodal epidermal mechanosensors based on a sequential “femtosecond laser patterning‐elastomer infiltration‐physical transfer” process. The resilient mechanosensor features a unique hybrid sensing layer of rigid cellular graphitic flakes (CGF)‐soft elastomer. The continuous microcracking of CGF under strain enables a sharp reduction in conductive pathways, while the soft elastomer within the framework sustains mechanical robustness of the structure. As a result, the mechanosensor achieves an ultrahigh sensitivity in a broad strain range (GF of 371.4 in the first linear range of 0–50%, and maximum GF of 8922.6 in the range of 61–70%), a low detection limit (0.01%), and a fast response/recovery behavior (2.6/2.1 ms). The device also exhibits excellent sensing performances to multimodal mechanical stimuli, enabling high‐fidelity monitoring of full‐range human motions. As proof‐of‐concept demonstrations, multi‐pixel mechanosensor arrays are constructed and implemented in a robot hand controlling system and a security system, providing a platform toward efficient HMIs.