The relationship between the atmospheric concentration of cosmogenic isotopes, the change of solar activity and hence secondary neutron flux has already been proven. The temporal atmospheric variation of the most studied cosmogenic isotopes shows a significant anti-correlation with solar cycles. However, since artificial tritium input to the atmosphere due to nuclear-weapon tests masked the expected variations of tritium production rate by three orders of magnitude, the natural variation of tritium in meteoric precipitation has not previously been detected. For the first time, we provide clear evidence of the positive correlation between the tritium concentration of meteoric precipitation and neutron flux modulated by solar magnetic activity. We found trends in tritium time series for numerous locations worldwide which are similar to the variation of secondary neutron flux and sun spot numbers. This variability appears to have similar periodicities to that of solar cycle. Frequency analysis, cross correlation analysis, continuous and cross wavelet analysis provide mathematical evidence that the correlation between solar cycle and meteoric tritium does exist. Our results demonstrate that the response of tritium variation in precipitation to the solar cycle can be used to help us understand its role in the water cycle.

Provalata Cave (Republic of Macedonia) is a small but remarkable hypogenic cave, developed in Cambrian marbles by successive thermal carbonic and sulfuric acid speleogenesis. The cave has a thick partly corroded calcite crust, abundant gypsum deposits, with cupolas, ceiling and wall channels, feeders and replacement pockets as some of the most characteristic morphological features. Distribution of morphology and deposits suggest a hypogenic origin in two distinct speleogenetic phases: the first by thermal CO2 rich waters, the second by sulfuric acid dissolution, which were separated by complete infilling of cave passages with pyroclastic-derived clays. In the first phase of speleogenesis, cave passages were formed by dissolution along fractures due to cooling of rising carbonated thermal waters. These phreatic morphologies were later covered with a thick calcite crust deposited in a shallow phreatic environment. In Early Pleistocene the cave was completely filled with clays due to deposition of pyroclastic rocks in a lacustrine environment in the nearby Mariovo Basin. Mariovo Lake sediments were later incised by the Buturica River, which cut down into Cambrian marbles, creating its superimposed valley. Incision lowered the water table and allowed removal of the clay deposits in Provalata Cave. The second phase of speleogenesis started after introduction of H2S associated with rising thermal waters. Oxidation produced sulfuric acid, which rapidly dissolved first calcite crust, then marble host rock. Condensation-corrosion by sulfuric vapors replaced carbonate rock with gypsum producing replacement pockets as well as second generation of pockets and cupolas. The contact of sulfuric acid with the clay deposits formed alunite, jarosite, and natroalunite. 40Ar/39Ar dating gave maximum ages of 1.6 Ma (alunite) and 1.46 Ma (jarosite) for this last stage of speleogenesis, thus making it the second 40Ar/39Ar dating of a sulfuric cave in Europe (after Kraushöhle in Austria), and the first dated cave in the Republic of Macedonia.

Although glacial landforms on the Balkan Peninsula have been studied since the 19th century, only scarce data are available about the extent of the former glaciations in the Central Balkan Peninsula, the transition zone between the Mediterranean and Central Europe. Glacial features of the Jablanica Mt. were mapped, described and classified into morphostratigraphic units. A revised glacio-geomorphological map was produced and glacial landforms were assigned to six morphostratigraphic units. Ten primary and two secondary cirques were identified in the upper parts of the studied valleys, while downstream the valleys were steep and glacially shaped with several glacial steps and thresholds. Cirque and valley morphology indicate that subglacial deepening was limited within the cirques and was more intensive in the valley sections during more extensive glacial phases. The largest reconstructed glaciers were 4.6–7 km long, while the last cirque glaciers were only a few hundred meters long. Using morphostratigraphic data, a glacier reconstruction was carried out for the largest mapped glacial extent. On the basis of glacial geomorphology, a former equilibrium-line altitude (ELA) of ~1800 m and glacier cover of 22.6 km² were estimated during this stage. The local ELA values were compared to the regional ELA record and enabled to tentatively attribute a MIS 6 age for the reconstructed maximum ice extent in the study area.