Impact diamonds were discovered in the 70s and are usually accepted as being paramorphs after graphite, resulting in grains of extremely high mechanical quality. A diffusion-less mechanism for the graphite-to-diamond transition under huge pressure has been experimentally realized and theoretically explained. Besides, another type of impact product has received much less attention, namely diamonds formed after coal as a result of the impact. Here we describe after-coal impact diamonds from the giant Kara astrobleme (Pay-Khoy, Russia), which resulted from a large asteroid impact about 70 Ma ago. The impact created a large number of unusual impact diamonds, which are described here for the first time using high-resolution techniques including visible and UV Raman spectroscopy, scanning electron microscopy (SEM), atomic force microscopy (AFM) and transmission electron microscopy (TEM). Two main varieties of after-coal diamonds occur: micrograined (sugar-like, subdivided into coherent and friable) and, as a new type, paramorphs after organic relics. After-coal diamonds differ from after-graphite impact diamonds by the texture, the absence of lonsdaleite, a micro- and nanoporous structure. The sugar-like variety consists of tightly aggregated, well-shaped single nanocrystals. The after-organic diamond paramorphs are characterized by a well-preserved relict organic morphology, sub- nanocrystalline–amorphous sp³-carbon (ta-C) nanocomposites and other specific properties (optical transparence, brown color, very high luminescence, spectral features). Based on the description of after-coal diamonds, we propose a new, polystage formation mechanism: high-velocity coal pyrolysis with hetero-elements removal followed by diffusion-limited crystallization of pure carbon. The similarity of the after-coal diamonds features with carbonado is a strong piece of evidence in support of the impact hypothesis for the origin of carbonado.

The existence of a new type of natural lonsdaleite confined to regionally metamorphosed and metasomatically modified rocks is verified based on complex data obtained by high resolution microscopy and spectroscopy. The structural and spectroscopic characteristics of isolated lonsdaleite particles that have a relatively large size and monocrystalline structure are given for the first time. The results of these studies can be used not only for simulating the processes of natural diamond formation, but also for designing superhard materials with allowance for the fact that lonsdaleite is the hardest material on Earth.

The state of substances under ultrahigh pressures and temperatures (UHPHT) now raises a special interest as a matter existing under extreme conditions and as potential new material. Under laboratory conditions only small amounts of micrometer-sized matter are produced at a pressure up to 100 GPa and at room temperature. Simultaneous combination of ultrahigh pressures and temperatures in a lab still requires serious technological effort. Here we describe the composition and structure of the UHPHT vein-like impact glass discovered by us in 2015 on the territory of the Kara astrobleme (Russia) and compare its properties with impact glass from the Ries crater (Germany). A complex of structural and spectroscopic methods presents unusual high pressure marks of structural elements in 8-fold co-ordination that had been described earlier neither in synthetic nor natural glasses. The Kara natural UHPHT glasses being about 70 Ma old have well preserved initial structure, presenting some heterogeneity as a result of partial liquation and crystallization differentiation where an amorphous component is proposed to originate from low level polymerization. Homogeneous parts of the UHPHT glasses can be used to deepened fundamental investigation of a substance under extreme PT conditions and to technological studies for novel material creations.

—Lavas of the Kamchatka volcanoes store cubic-octahedral diamonds identical in morphology and structure to synthetic crystals, and their natural origin is doubted. Judging by published data, the diamonds discovered in the Tolbachik lavas are similar to synthetic diamonds made by different producers, and the analyzed samples rather result from contamination with synthetic material. Ophiolite-hosted diamonds reported from Europe, China, Mongolia, and Polar Urals look like the Tolbachik diamonds and are of the same type. The similarity between crystals coming from geologically dissimilar objects indicates that contamination may occur in those cases as well. Thus, diamonds found in unusual hosts or geologic settings require careful checking. These findings have to be reproduced repeatedly in other in situ samples and approved by independent experts; with all respect to the priority of the first finders, the sampling sites should be open to many researchers, especially the respective specialists. The inevitable disproval of false diamond findings is discouraging and discredits the true discoveries. Possible contamination with synthetic or natural material from cutting tools has to be excluded in all newly found diamonds before claiming their natural origin.