Bivalve shells, available in abundance, have no eminent use and are commonly regarded as waste. Their improper disposal causes a significant level of environmental concern and also results in a waste of natural resources. Bivalve shell is formed by biomineralization and consists mainly of CaCO3 with a small amount of organic matrix, giving it a potential for use as raw material. Recycling shell waste could potentially eliminate the disposal problem, and also turn an otherwise useless waste into high value-added products. The present paper first describes the microstructure and physicochemical properties of bivalve shell, then focuses on its current applications. Finally, the current status of bivalve shell studies and directions for future research are considered.
1 January 2022 in Science of The Total Environment
In this work, the pyrolysis behavior of plastic waste—TV plastic shell—was investigated, based on thermogravimetric analysis and using a combination of model-fitting and model-free methods. The possible reaction mechanism and kinetic compensation effects were also examined. Thermogravimetric analysis indicated that the decomposition of plastic waste in a helium atmosphere can be divided into three stages: the minor loss stage (20–300°C), the major loss stage (300–500°C) and the stable loss stage (500–1000°C). The corresponding weight loss at three different heating rates of 15, 25 and 35 K/min were determined to be 2.80–3.02%, 94.45–95.11% and 0.04–0.16%, respectively. The activation energy ( Ea) and correlation coefficient ( R2) profiles revealed that the kinetic parameters calculated using the Friedman and Kissinger–Akahira–Sunose method displayed a similar trend. The values from the Flynn–Wall–Ozawa and Starink methods were comparable, although the former gave higher R2 values. The Eα values gradually decreased from 269.75 kJ/mol to 184.18 kJ/mol as the degree of conversion ( α) increased from 0.1 to 0.8. Beyond this range, the Eα slightly increased to 211.31 kJ/mol. The model-fitting method of Coats–Redfern was used to predict the possible reaction mechanism, for which the first-order model resulted in higher R2 values than and comparable Eα values to those obtained from the Flynn–Wall–Ozawa method. The pre-exponential factors (ln A) were calculated based on the F1 reaction model and the Flynn–Wall–Ozawa method, and fell in the range 59.34–48.05. The study of the kinetic compensation effect confirmed that a compensation effect existed between Ea and ln A during the plastic waste pyrolysis.
The unchecked growth of Eichhornia crassipes can cause significant harm, including covering of the water surface, depletion of oxygen, clogging of river channels, and promotion of the breeding of flies and mosquitoes. These effects can significantly impact farmland irrigation, water transportation, and human health. However, methods for controlling its growth are not ideal, and control using biological and chemical agents can result in secondary pollution. The utilization of E. crassipes as a resource, for example, as animal feed or organic substrates, can not only turn waste into valuable resources, but it can also solve the problem of its growth, thus bringing about economic and ecological benefits. In this paper, the growth and ecological characteristics of E. crassipes, its nutrient composition, and resource utilization approaches were reviewed. The challenges associated with the large-scale utilization of E. crassipes were also analyzed in order to provide references for the control and resource utilization of the species. Regarding challenges such as the difficulty of cultivation and the high cost of harvesting and dehydrating, it is necessary to investigate the proper water surface and coverage characteristics of E. crassipes cultivation to assure adequate biomass and protect the ecological landscape. It is also necessary to evaluate the effect of E. crassipes cultivation on the health of aquatic ecosystems and the safety of the water environment in order to prevent the significant potential ecological and environmental risks. In addition, developing portable, high-efficiency facilities to promote the effectiveness of harvesting, transportation and dehydration are needed, as well as further improvement in the techniques of utilization and assessment of the economic value.