Silver nanoparticles capped with 3-mercapto-1propanesulfonic acid sodium salt (AgNPs-3MPS), able to interact with Ni²⁺ or Co²⁺, have been prepared to detect these heavy metal ions in water. This system works as an optical sensor and it is based on the change of the intensity and shape of optical absorption peak due to the surface plasmon resonance (SPR) when the AgNPs-3MPS are in presence of metals ions in a water solution. We obtain a specific sensitivity to Ni²⁺ and Co²⁺ up to 500 ppb (part per billion). For a concentration of 1 ppm (part per million), the change in the optical absorption is strong enough to produce a colorimetric effect on the solution, easily visible with the naked eye. In addition to the UV-VIS characterizations, morphological and dimensional studies were carried out by transmission electron microscopy (TEM). Moreover, the systems were investigated by means of dynamic light scattering (DLS), Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and high-resolution X-ray photoelectron spectroscopy (HR-XPS). On the basis of the results, the mechanism responsible for the AgNPs-3MPS interaction with Ni²⁺ and Co²⁺ (in the range of 0.5–2.0 ppm) looks like based on the coordination compounds formation.

We report on synthesis of silver nanoparticles (AgNPs) capped with specific thiol suitable to detect heavy metal ions in water. The sensing mechanism is based on a change of an optical properties of the silver colloids, namely the surface plasmon resonance (SPR) when small amounts of contaminants are present in solution. We detected a specific sensitivity to nickel ions and we investigated the interaction of the AgNPs with Ni²⁺ in the concentration range of 0.5–2.0 ppm.