Quickly and efficiently monitoring soil nutrient contents using remote sensing technology is of great significance for farmland soil productivity, food security and sustainable agricultural development. Current research has been conducted to estimate and map soil nutrient contents in large areas using hyper-spectral techniques, however, it is difficult to obtain accurate estimates. In order to improve the estimation accuracy of soil nutrient contents, we introduced a GA-BPNN method, which combined a back propagation neural network (BPNN) with the genetic algorithm optimization (GA). This study was conducted in Guangdong, China, based on soil nutrient contents and hyperspectral data. The prediction accuracies from a partial least squares regression (PLSR), BPNN and GA-BPNN were compared using field observations. The results showed that (1) Among three methods, the GA-BPNN provided the most accurate estimates of soil total nitrogen (TN), total phosphorus (TP) and total potassium (TK) contents; (2) Compared with the BPNN models, the GA-BPNN models significantly improved the estimation accuracies of the soil nutrient contents by decreasing the relative root mean square error (RRMSE) values by 15.9%, 5.6% and 20.2% at the sample point level, and 20.1%, 16.5% and 47.1% at the regional scale for TN, TP and TK, respectively. This indicated that by optimizing the parameters of BPNN, the GA-BPNN provided greater potential to improving the estimation; and (3) Soil TK content could be more accurately mapped by the GA-BPNN method using HuanJing-1A Hyperspectral Imager (HJ-1A HSI) (manufacturer: China Aerospace Science and Technology Corporation; Beijing, China) data with a RRMSE value of 20.37% than the soil TN and TP with the RRMSE values of 40.41% and 34.71%, respectively. This implied that the GA-BPNN model provided the potential to map the soil TK content for the large area. The research results provided an important reference for high-accuracy prediction of soil nutrient contents.

Quickly and efficiently monitoring soil heavy metal content is crucial for protecting the natural environment and for human health. Estimating heavy metal content in soils using hyperspectral data is a cost-efficient method but challenging due to the effects of complex landscapes and soil properties. One of the challenges is how to make a lab-derived model based on soil samples applicable to mapping the contents of heavy metals in soil using air-borne or space-borne hyperspectral imagery at a regional scale. For this purpose, our study proposed a novel method using hyperspectral data from soil samples and the HuanJing-1A (HJ-1A) HyperSpectral Imager (HSI). In this method, estimation models were first developed using optimal relevant spectral variables from dry soil spectral reflectance (DSSR) data and field observations of soil heavy metal content. The relationship of the ratio of DSSR to moisture soil spectral reflectance (MSSR) with soil moisture content was then derived, which built up the linkage of DSSR with MSSR and provided the potential of applying the models developed in the laboratory to map soil heavy metal content at a regional scale using hyperspectral imagery. The optimal relevant spectral variables were obtained by combining the Boruta algorithm with a stepwise regression and variance inflation factor. This method was developed, validated, and applied to estimate the content of heavy metals in soil (As, Cd, and Hg) in Guangdong, China, and the Conghua district of Guangzhou city. The results showed that based on the validation datasets, the content of Cd could be reliably estimated and mapped by the proposed method, with relative root mean square error (RMSE) values of 17.41% for the point measurements of soil samples from Guangdong province and 17.10% for the Conghua district at the regional scale, while the content of heavy metals As and Hg in soil were relatively difficult to predict with the relative RMSE values of 32.27% and 28.72% at the soil sample level and 51.55% and 36.34% at the regional scale. Moreover, the relationship of the DSSR/MSSR ratio with soil moisture content varied greatly before the wavelength of 1029 nm and became stable after that, which linked DSSR with MSSR and provided the possibility of applying the DSSR-based models to map the soil heavy metal content at the regional scale using the HJ-1A images. In addition, it was found that overall there were only a few soil samples with the content of heavy metals exceeding the health standards in Guangdong province, while in Conghua the seriously polluted areas were mainly distributed in the cities and croplands. This study implies that the new approach provides the potential to map the content of heavy metals in soil, but the estimation model of Cd was more accurate than those of As and Hg.

Mercury is one of the five most toxic heavy metals to the human body. In order to select a high-precision method for predicting the mercury content in soil using hyperspectral techniques, 75 soil samples were collected in Guangdong Province to obtain the soil mercury content by chemical analysis and hyperspectral data based on an indoor hyperspectral experiment. A multiple linear regression (MLR), a back-propagation neural network (BPNN), and a genetic algorithm optimization of the BPNN (GA-BPNN) were used to establish a relationship between the hyperspectral data and the soil mercury content and to predict the soil mercury content. In addition, the feasibility and modeling effects of the three modeling methods were compared and discussed. The results show that the GA-BPNN provided the best soil mercury prediction model. The modeling $R^2$ is 0.842, the root mean square error (RMSE) is 0.052, and the mean absolute error (MAE) is 0.037; the testing $R^2$ is 0.923, the RMSE is 0.042, and the MAE is 0.033. Thus, the GA-BPNN method is the optimum method to predict soil mercury content and the results provide a scientific basis and technical support for the hyperspectral inversion of the soil mercury content.

Soil nutrients play a vital role in plant growth and thus the rapid acquisition of soil nutrient content is of great significance for agricultural sustainable development. Hyperspectral remote-sensing techniques allow for the quick monitoring of soil nutrients. However, at present, obtaining accurate estimates proves to be difficult due to the weak spectral features of soil nutrients and the low accuracy of soil nutrient estimation models. This study proposed a new method to improve soil nutrient estimation. Firstly, for obtaining characteristic variables, we employed partial least squares regression (PLSR) fit degree to select an optimal screening algorithm from three algorithms (Pearson correlation coefficient, PCC; least absolute shrinkage and selection operator, LASSO; and gradient boosting decision tree, GBDT). Secondly, linear (multi-linear regression, MLR; ridge regression, RR) and nonlinear (support vector machine, SVM; and back propagation neural network with genetic algorithm optimization, GABP) algorithms with 10-fold cross-validation were implemented to determine the most accurate model for estimating soil total nitrogen (TN), total phosphorus (TP), and total potassium (TK) contents. Finally, the new method was used to map the soil TK content at a regional scale using the soil component spectral variables retrieved by the fully constrained least squares (FCLS) method based on an image from the HuanJing-1A Hyperspectral Imager (HJ-1A HSI) of the Conghua District of Guangzhou, China. The results identified the GBDT-GABP was observed as the most accurate estimation method of soil TN ( of 0.69, the root mean square error of cross-validation (RMSECV) of 0.35 g kg⁻¹ and ratio of performance to interquartile range (RPIQ) of 2.03) and TP ( of 0.73, RMSECV of 0.30 g kg⁻¹ and RPIQ = 2.10), and the LASSO-GABP proved to be optimal for soil TK estimations ( of 0.82, RMSECV of 3.39 g kg⁻¹ and RPIQ = 3.57). Additionally, the highly accurate LASSO-GABP-estimated soil TK (R² = 0.79) reveals the feasibility of the LASSO-GABP method to retrieve soil TK content at the regional scale.

Rapid and efficient assessment of cultivated land quality (CLQ) using remote sensing technology is of great significance for protecting cultivated land. However, it is difficult to obtain accurate CLQ estimates using the current satellite-driven approaches in the pressure-state-response (PSR) framework, owing to the limitations of linear models and CLQ spectral indices. In order to improve the estimation accuracy of CLQ, this study used four evaluation models (the traditional linear model; partial least squares regression, PLSR; back propagation neural network, BPNN; and BPNN with genetic algorithm optimization, GA-BPNN) to evaluate CLQ for determining the accurate evaluation model. In addition, the optimal satellite-derived indicator in the land state index was selected among five vegetation indices (the normalized vegetation index, NDVI; enhanced vegetation index, EVI; modified soil-adjusted vegetation index, MSAVI; perpendicular vegetation index, PVI; and soil-adjusted vegetation index, SAVI) to improve the prediction accuracy of CLQ. This study was conducted in Conghua District of Guangzhou, Guangdong Province, China, based on Gaofen-1 (GF-1) data. The prediction accuracies from the traditional linear model, PLSR, BPNN, and GA-BPNN were compared using observations. The results demonstrated that (1) compared with other models (the traditional linear model: R² = 0.14 and RMSE = 91.53; PLSR: R² = 0.33 and RMSE = 74.58; BPNN: R² = 0.50 and RMSE = 61.75), the GA-BPNN model based on EVI in the land state index provided the most accurate estimates of CLQ, with the R² of 0.59 and root mean square error (RMSE) of 56.87, indicating a nonlinear relationship between CLQ and the prediction indicator; and (2) the GA-BPNN-based evaluation approach of CLQ in the PSR framework was driven to map CLQ of the study area using the GF-1 data, leading to an RMSE of 61.44 at the regional scale, implying that the GA-BPNN-based evaluation approach has the potential to map CLQ over large areas. This study provides an important reference for the high-accuracy prediction of CLQ based on remote sensing technology.

This study was conducted to elucidate how changes in critical soil quality characteristics relate to continuous rice cultivation and changes in cropping systems and fertilization in South China over the time span 1980 to 2017. Soil pH, soil organic matter (SOM), total nitrogen (TN), available phosphorus (AP) and potassium (AK) were determined for the samples taken in 2017 and compared to results from the paired samples collected in 1980 by grouping all samples into four cropping systems: continuous paddy fields, new paddy fields developed from uplands, continuous uplands, and new uplands developed from paddy soils. The results show a significant increase in soil pH, AP and AK in all cropping systems, which was, however, coupled with low fertilizer use efficiency. Additionally, a significant increase in SOM came with new paddy soils, whereas a little SOM accumulation and a significantly weakened correlation of TN to SOM occurred in continuous paddy soils. Both low fertilizer use efficiency and deteriorated soil C sequestration function imply a sub-health status of continuous paddy soils. The changes in cropping systems and fertilization, which essentially resulted from expeditious economic growth, should be responsible for the dynamics of C and N and the consequences to soil quality. More experimental studies on balanced fertilization vs. local commonly used fertilization are suggested to probe the mechanisms underlying the C and N dynamics in paddy soils.