Under a combination of AgSR with a copper source, sulfur-substituted benzenoid quinones were prepared in high yields (generally >90%). The compounds have presented significant activity againstT. cruzi, the etiologic agent of Chagas disease.
A unique bistable copper-metallacyclic complex is used as an elegant molecular switch for the reversible formation of emulsions by simple pH variation. This switch may have several exciting applications in biphasic processes such as catalysis and separation science technologies.
Despite high photo-conversion efficiency, the short long-term stability and toxicity issues have prevented lead-based perovskites from becoming the standard in high efficiency solar cells.