This study aimed to enhance the mechanical properties of calcium sulfoaluminate cement grouting materials (HCSA) by investigating the effects of ordinary Portland cement (OPC) content, the ratio of quicklime to gypsum, and the dosage of sodium aluminate on the compressive strength of the OPC-CSA composite system. The results indicate that as the OPC content increases, the compressive strength of the blended cement initially increases and then decreases, reaching a maximum at a 60% OPC replacement ratio within the experimental group. The addition of an appropriate amount of OPC to the CSA composite system effectively prevents the regression of compressive strength. With an increase in quicklime content, the compressive strength of the samples at various ages first increases and then decreases, with the optimal ratio of quicklime to gypsum found to be 2:8. Furthermore, sodium aluminate, used as an activator, when increased in dosage, leads to an initial increase followed by a decrease in the compressive strength of OPC-CSA samples, with an optimal incorporation rate of 0.75%, significantly enhancing the strength of the blended cement. In the orthogonal experiments, the dosage of sodium aluminate was identified as the most influential factor affecting the compressive strength of the composite grouting materials.
5 December 2024 in International Journal of Concrete Structures and Materials
The binary phase change paraffin (BP) was prepared using the melt blending method, followed by adsorption and encapsulation to produce the phase change aggregate. Phase change concrete was subsequently prepared using the volumetric replacement method. The study examined the thermal properties of BP, along with the semi-adiabatic temperature rise and thermal conductivity of the phase change concrete at different replacement rates. The results indicate that BP exhibits two plateau regions, with phase change intervals varying according to the mass ratio. The high-temperature phase change interval ranges from 18.3 °C to 47.3 °C, while the low-temperature phase change interval ranges from 0.1 °C to 4.6 °C. When the mass ratio of 48# paraffin to 5# paraffin is 7:3, the peak phase change temperatures are 2.58 °C and 44.52 °C, with corresponding enthalpies of 66.52 J/g and 102.63 J/g, respectively. The addition of phase change aggregate effectively reduces the hydration temperature rise of concrete, slows the rate of temperature increase, and decreases the thermal conductivity. The semi-adiabatic temperature rise curve of the phase change concrete exhibits an "S"-shaped variation over time, with the composite exponential function providing a more accurate representation of this process.
12 March 2026 in International Journal of Concrete Structures and Materials
Phase change materials (PCMs) can mitigate early age thermal cracking in mass concrete but usually reduce mechanical strength due to their low stiffness an
In order to study the changes in the mechanical properties of road subgrade in cold areas after the freezing and thawing of highways in cold areas, indoor mechanical tests were carried out to investigate the effects of the number of freeze–thaw cycles, freezing temperature, water content, and circumferential pressure on the mechanical properties of road subgrade soil in cold areas after thawing. The mechanical properties of road subgrade soil in cold areas after thawing were measured under different conditions. The test results show that, within the study range: (1) After 7 freeze–thaw cycles, the destructive stress of the subgrade soil decreased from 321.7 kPa to 289.9 kPa, a decrease of 9.9%, and the elastic modulus decayed by 19.9%. (2) When the freezing temperature was reduced from −5 °C to −15 °C, the destructive stress of the subgrade soil decreased from 303.9 kPa to 290.1 kPa, a decrease of 13.8 kPa, approximately 4.5%, and the decrease in modulus of elasticity was about 1.6%. (3) The water content increased from 6% to 12%, and the destructive stress decreased from 405.43 kPa to 288.4 kPa, a decrease of 29.1%, and the modulus of elasticity decreased approximately linearly, with an attenuation of 50.4%. (4) The peripheral pressure increased from 50 kPa to 150 kPa, and the destructive stress increased from 194.7 kPa to 367.7 kPa, a growth of 88.8%, and its modulus of elasticity increased with the increase in peripheral pressure, an increase of 154.1%. The results of this research can provide a reference for highway and engineering construction in the western silt–soil distribution area.
This study aimed to enhance the slurry performance and durability of coal gangue-based geopolymers (CGGP) by incorporating four types of nanomaterials: nano-SiO2 (NS), graphene oxide (GO) nanosheets, nano-CaCo3 (NC), and nano-Al2O3 (NA). The microstructure and underlying mechanisms were thoroughly investigated using scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). The results indicate that the type and dosage of nanomaterials significantly influence the rheological properties, strength development, setting time, porosity, and water absorption of CGGP. Specifically, the addition of GO nanosheets drastically reduced fluidity, with a 73.33% decrease in flowability compared to the control group at a 2.0 wt.% dosage. Nano-SiO2 exhibited the most pronounced effect in improving compressive strength and shortening the setting time, with the optimal accelerating effect observed at a 1.5 wt.% dosage. Nano-CaCO3 primarily acts as a filler. Though its reactivity is relatively low, at an appropriate dosage (1.5 wt.%), it can effectively reduce porosity and water absorption. Moreover, at a dosage of 1 wt.%, it exhibits the optimal 28-day compressive strength, which is 54.18% higher than that of the blank group. Nano-Al2O3 demonstrated a relatively stable accelerating effect on setting and yielded the best pore structure and strength at a 1.5 wt.% dosage. SEM analysis revealed that the incorporation of an appropriate amount of NC particles significantly improved the microstructural densification of the polymer. Concurrently, EDS results confirmed the positive influence of the nano-Al2O3 material on the distribution of hydration products and the interfacial structure. This research provides an important theoretical basis and technical support for the high-performance design and widespread engineering application of coal gangue-based geopolymers.
In this study, phase change materials (PCMs) were innovatively incorporated into hybrid fiber concrete. The properties of PCMs, which absorb and release heat during phase transitions, enable the concrete to actively respond to complex and varying temperature environments. This integration reduces the internal temperature differentials within the concrete, thereby preventing temperature-induced cracks in deep wellbore structures. Through the temperature control model test of the frozen shaft wall, it can be seen that the hybrid fiber phase change concrete (HFPCC) significantly reduces the internal temperature difference, and the maximum temperature difference along the radial direction is 35.84% lower than that of benchmark concrete (BC). The numerical simulation results indicate that a moderate phase transition temperature should be selected in engineering. The phase change temperature should not be close to the ambient temperature and peak temperature. The peak temperature can be reduced by 9.32% and the maximum radial temperature difference can be reduced by 30.89% by selecting an appropriate phase change temperature. The peak temperature and radial maximum temperature difference are both proportional to the latent heat of phase change. The temperature control performance of phase change concrete can be further improved by increasing the latent heat of phase change materials.