Despite significant progress in photoelectrochemical (PEC) water splitting, high fabrication costs and limited efficiency of photoanodes hinder practical applications. Bismuth vanadate (BiVO₄), with its low cost, non-toxicity, and suitable band structure, is a promising photoanode material but suffers from poor charge transport, sluggish surface kinetics, and photocorrosion. In this study, porous monoclinic BiVO₄ films are fabricated via a simplified successive ionic layer adsorption and reaction (SILAR) method, followed by borate treatment and PEC deposition of NiFeO_x. The resulting B/BiVO₄/NiFeO_x photoanode exhibits a significantly enhanced photocurrent density of 2.45 mA cm⁻² at 1.23 V vs. RHE—5.3 times higher than pristine BiVO₄. It also achieves an ABPE of 0.77% and a charge transfer efficiency of 79.5%. These results demonstrate that dual surface modification via borate and NiFeO_x is a cost-effective strategy to improve BiVO₄-based PEC water splitting performance. This work provides a promising pathway for the scalable development of efficient and economically viable photoanodes for solar hydrogen production.