Valery Kulichikhin

Prof. Valery Kulichikhin

A.V.Topchiev Institute of Petrochemical Synthesis RAS
orcid

Research Focus & Metrics

Academic Career Length

56Years (1971-Present)

(Calculated once Scilit publication data is synced: current year − year of first publication + 1)

Representative Publications

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3 September 2023 in Gels
Verified
Journal Article
Open access
PDF file
Alexander MalkinAlexander Malkin
Alexander Malkin
Svetlana R. DerkachSvetlana R. Derkach
Svetlana R. Derkach
Valery KulichikhinValery Kulichikhin
Valery Kulichikhin
In this review, today’s state of the art in the rheology of gels and transition through the yield stress of yielding liquids is discussed. Gels are understood as soft viscoelastic multicomponent solids that are in the incomplete phase separation state, which, under the action of external mechanical forces, do not transit into a fluid state but rupture like any solid material. Gels can “melt” (again, like any solids) due to a change in temperature or variation in the environment. In contrast to this type of rheology, yielding liquids (sometimes not rigorously referred to as “gels”, especially in relation to colloids) can exist in a solid-like (gel-like) state and become fluid above some defined stress and time conditions (yield stress). At low stresses, their behavior is quite similar to that of permanent solid gels, including the frequency-independent storage modulus. The gel-to-sol transition considered in colloid chemistry is treated as a case of yielding. However, in many cases, the yield stress cannot be assumed to be a physical parameter since the solid-to-liquid transition happens in time and is associated with thixotropic effects. In this review, special attention is paid to various time effects. It is also stressed that plasticity is not equivalent to flow since (irreversible) plastic deformations are determined by stress but do not continue over time. We also discuss some typical errors, difficulties, and wrong interpretations of experimental data in studies of yielding liquids.

1 September 2015 in LWT
Verified
Journal Article
Closed access
SDSvetlana Rostislavovna Derkach
Svetlana Rostislavovna Derkach
Sergey O. IlyinSergey O. Ilyin
Sergey O. Ilyin
AMAlexandra Alexandrovna Maklakova
Alexandra Alexandrovna Maklakova
Valery KulichikhinValery Kulichikhin
Valery Kulichikhin
AMAlexander Yakovlevich Malkin
Alexander Yakovlevich Malkin

1 November 2016 in Journal of Petroleum Science and Engineering
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Journal Article
Closed access
Sergey O. IlyinSergey O. Ilyin
Sergey O. Ilyin
MAMarianna Arinina
Marianna Arinina
MPMariya Polyakova
Mariya Polyakova
GBGalina Bondarenko
Galina Bondarenko
IKIvan Konstantinov
Ivan Konstantinov
AMAlexander Malkin
Alexander Malkin

23 September 2016 in Rheologica Acta
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Journal Article
Closed access
PDF file
Alexander MalkinAlexander Malkin
Alexander Malkin
Valery KulichikhinValery Kulichikhin
Valery Kulichikhin
Sergey O. IlyinSergey O. Ilyin
Sergey O. Ilyin

30 April 2013 in Russian Chemical Reviews
Verified
Journal Article
Closed access
VGV A Gerasin
V A Gerasin
EAEvgenii M Antipov
Evgenii M Antipov
VKV V Karbushev
V V Karbushev
Valery KulichikhinValery Kulichikhin
Valery Kulichikhin
GKGalina P Karpacheva
Galina P Karpacheva
YKY V Kudryavtsev
Y V Kudryavtsev

1 December 2016 in Fuel
Verified
Journal Article
Closed access
Sergey O. IlyinSergey O. Ilyin
Sergey O. Ilyin
MAM.P. Arinina
M.P. Arinina
MPM.Yu. Polyakova
M.Yu. Polyakova
Valery KulichikhinValery Kulichikhin
Valery Kulichikhin
AMA.Ya. Malkin
A.Ya. Malkin