Oriental Journal of Chemistry is a peer reviewed quarterly research journal of pure and applied chemistry. It publishes standard research papers in almost all thrust areas of current chemistry of academic and commercial importance. It provides a platform for rapid publication of quality research papers, reviews and chemistry letters. Oriental Journal of Chemistry is abstracted and indexed in almost all reputed National and International agencies.
1 February 1996 in Polymer Degradation and Stability
The purpose of this study was to investigate the adsorption ability of activated carbon from rice husk in adsorbing phenol. Activated carbon used was in this studies burning risk husk at 300 and 400oC and then activated by 10% of ZnCl2. The from activated carbon was characterized using an Infrared Spectrometer, an X-ray diffraction, an Scanning Electron Microscope, and a gas sorption analyzer. The best activated carbon for adsorbing phenol was the activated carbon that prodused from the burning of rice husk at a temperature 400oC and activated with 10% of ZnCl2 for 24 hours. Adsorption capacity of the best activated carbon was 3.9370 mg/g adsorbent with Gibbs free energy of -25.493 kJ/mol.
31 July 2019 in Indonesian Journal of Chemical Research
Silver nanoparticles have been synthesized by the reduction method using salam leaf extract (Syzygium polyanthum) as a reducing agent. The silver nanoparticles produced were then tested for their activity as antioxidants. The formation of silver nanoparticles was carried out by adding the leaf extract into the solution of AgNO3 and homogenized using a magnetic stirrer. A UV-Vis spectrophotometer was used to confirm the formation of silver nanoparticles. Particle Size Analyzer (PSA), Scanning Electron Microscope (SEM), X-Ray Diffractometer (XRD) and Fourir Transform Infra Red (FTIR) spectrometers were used to characterize the nanoparticles produced before being tested for antioxidant activity. The results showed that the absorbance value increased with increasing reaction contact time. The maximum uptake was obtained at wavelengths of 432-446 nm using a UV-Vis spectrophotometer. The particle size was determined using a PSA with an average particle size distribution of 45.7 nm. The average diameter of silver nanoparticles was 10.06 – 13.97 nm and the silver nanoparticles had rod-shapes. Functional groups that play a role in the synthesis of nanoparticles were –OH, –C=O, and –C-O groups. Silver nanoparticles inhibited free radicals as antioxidants with the IC50 value of 582.7 ppm.
Research was conducted on the role of brown algae as a capping agent in the synthesis of ZnO nanoparticles, the characteristics of ZnO nanoparticles, and the effect of the addition of ZnO nanoparticles and/or silane compounds on antibacterial and antifungal activities. The synthesis of ZnO nanoparticles involved green synthesis, and then nanoparticles were characterized using UV/VIS/NIR, ATR-FTIR, XRD, PSA, and SEM-EDS, followed by the in situ deposition of ZnO nanoparticles on cotton fabrics and the addition of silane compounds. The characterization of modified and unmodified cotton fabrics and antibacterial and antifungal activity tests were carried out using the disc diffusion method through measurements of the diameter of the inhibition zone against Pseudomonas aeruginosa, Staphylococcus epidermidis, and Malassezia furfur. The characterization of ZnO nanoparticles showed absorption at a wavelength of 357 nm; the number of waves was 450 cm−1; the diffraction peak occurred at an angle of 36.14°; the crystal size was 15.35 nm; there was a heterogeneous particle distribution; the particle size was in the ranges of 1.74–706 nm (PSA) and 45–297 nm (SEM); and an irregular particle shape was noted. The results showed that the best antibacterial and antifungal activity was obtained in cotton + HDTMS + ZnO nanoparticles (K8) and cotton + ZnO nanoparticles+HDTMS/MTMS (K4).