A highly efficient adsorbent for methylene blue (MB) adsorption was developed by combination of carboxymethyl cellulose (CMC) and graphene oxide (GO) via a simple one-step hydrothermal method. The as-synthesized CMC/GO composite aerogel has a mesoporous structure with an average pore diameter of 30 nm and a high specific surface area of 800.85 m²·g⁻¹. Moreover, the CMC/GO composite aerogel demonstrates a significant selectivity for the dye adsorption, especially for MB, where its adsorption capacity can reach 244.99 mg·g⁻¹ with an excellent recyclability for more than nine times. Thus, the prepared CMC/GO composite aerogel would be an effective adsorbent for dyes adsorption, owing to the merits of high efficiency, reusability, and eco-friendliness.

Graphene based aerogel has become one of the most likely functional adsorption materials that is applicable to purify various contaminated water sources, such as dye wastewater, because of its high porosity, structural stability, large specific surface area, and high adsorption capacity. In this study, chitosan and graphene oxide were first selected as the matrix to prepare the composite hydrogel through the hydrothermal method, which was further frozen and dried to obtain the target aerogel. The microscopic structures and adsorption capacity of the composite aerogel were then characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), X-ray powder diffraction (XRD) and N₂ (nitrogen) physical adsorption and desorption tests. The results show that the specific surface area of the composite aerogel was reached at 297.431 m²/g, which is higher than that of graphene oxide aerogel and chitosan aerogel. The aperture was reduced to about 3 nm. The adsorption rate of the composite aerogel for the methyl orange solution was as high as 97.2% at pH = 1, and the adsorption capacity was 48.6 mg/g. The adsorption process of the composite aerogel satisfies the Langmuir equation and can be described by the second-order adsorption kinetics. In addition, it is worth noting that this composite aerogel can provide a striking adsorption characteristic on methyl orange due to the combining effects from massive amino groups on chitosan and the structural conjugation of graphene oxide.

Multifunctional polymer composites with both high dielectric constants and high thermal conductivity are urgently needed by high-temperature electronic devices and modern microelectromechanical systems. However, high heat-conduction capability or dielectric properties of polymer composites all depend on high-content loading of different functional thermal-conductive or high-dielectric ceramic fillers (every filler volume fraction ≥ 50%, i.e., f_filler ≥ 50%), and an overload of various fillers (f_{thermal-conductive filler} + f_{high-dielectric filler} > 50%) will decrease the processability and mechanical properties of the composite. Herein, series of alumina/barium titanate/polypropylene (Al₂O₃/BT/PP) composites with high dielectric- and high thermal-conductivity properties are prepared with no more than 50% volume fraction of total ceramic fillers loading, i.e., f_fillers ≤ 50%. Results showed the thermal conductivity of the Al₂O₃/BT/PP composite is up to 0.90 W/m·K with only 10% thermal-conductive Al₂O₃ filler, which is 4.5 times higher than the corresponding Al₂O₃/PP composites. Moreover, higher dielectric strength (E_b) is also found at the same loading, which is 1.6 times higher than PP, and the Al₂O₃/BT/PP composite also exhibited high dielectric constant ( ${\epsilon }_{\mathrm{r}}$ = 18 at 1000 Hz) and low dielectric loss (tan δ ≤ 0.030). These excellent performances originate from the synergistic mechanism between BaTiO₃ macroparticles and Al₂O₃ nanoparticles.

SEM images of Melamine-formaldehyde polymer microspheres (MF) (a) and Yb-doped TiO₂ hollow spheres (Yb-TiO₂HS) (b).