In this paper, the thermal conductivity behavior of synthetic and natural esters reinforced with 2D nanostructures—single hexagonal boron nitride (h-BN), single molybdenum disulfide (MoS₂), and hybrid h-BN/MOS₂—were studied and compared to each other. As a basis for the synthesis of nanofluids, three biodegradable insulating lubricants were used: FR3^TM and VG-100 were used as natural esters and MIDEL 7131 as a synthetic ester. Two-dimensional nanosheets of h-BN, MoS_2, and their hybrid nanofillers (50/50 ratio percent) were incorporated into matrix lubricants without surfactants or additives. Nanofluids were prepared at 0.01, 0.05, 0.10, 0.15, and 0.25 weight percent of filler fraction. The experimental results revealed improvements in thermal conductivity in the range of 20–32% at 323 K with the addition of 2D nanostructures, and a synergistic behavior was observed for the hybrid h-BN/MoS₂ nanostructures.

Carbon nanostructures have been recently applied to improve industrial manufacturing processes and other materials; such is the case for lubricants used in the metal-mechanic industry. Nanotori are toroidal carbon nanostructures, obtained from chemical treatment of multi-wall carbon nanotubes (MWCNTs). This material has been shown to have superb anti-wear and friction reduction performance, having the ability to homogeneously disperse within water in concentrations between 1–2 wt.%. Obtained results of these novel nanostructures under water mixtures and novel additives were a set point to our studies in different industrial lubricants. In the present work, nanotori structures have been applied in various filler fractions as reinforcement to evaluate the behavior in thermal transport of water-based (WB) and oil-based (OB) lubricants. Temperature-dependent experiments to evaluate the thermal conductivity were performed using a thermal water bath ranging from room temperature up to 323 K. The obtained results showed a highly effective and favorable improvement in the heat transport of both lubricants; oil-based results were better than water-based results, with nanotori structures increasing the lubricants’ thermal transport properties by 70%, compared to pure lubricant.

This research presents the effects of carbon nanotori structures (CNst) dispersed as reinforcement for metal-working and metal-forming lubricants. Synthetic (SL) and deep drawing (DD) nanolubricants were prepared following a two-step method at 0.01 wt.%, 0.05 wt.%, and 0.10 wt.% filler fractions. Slight increases in viscosity (<6%) for nanolubricants were observed as filler fraction was increased through various measured temperatures. Tribological behavior of nanolubricants displayed superb improvements under antiwear and extreme pressure conditions. The load carrying capacity (p_oz) increased by 16% and 22% at merely 0.01 wt.% CNst reinforcement and up to 73% and 107% at 0.10 wt.% filler fraction for SL and DD nanolubricants, respectively, compared to conventional materials. Additionally, at 0.10 wt.% wear scar evaluations showed a highest benefit of 16% and 24%, for SL and DD nanolubricants, respectively. This enhancement is attributed to diverse mechanisms such as rolling/sliding and load bearing effects, tribofilm formation, and CNst tribosintering behavior (at high pressures) onto metallic surfaces due to nanostructures size and morphology and their interlayer relationship among conventional lubricants.