A major goal for port authorities, operators, and investors is to achieve efficient operations and effective environmental protection. This is because the environmental performance of a container port is important for its competitiveness and sustainable development. However, the container ports along the Maritime Silk Road (MSR) have caused numerous problems with the rapid development, among which the most significant problem is environmental pollution. In this paper, we aim to measure and compare the environmental performance and operational efficiency of ten major container ports along the MSR, including the ports of Shanghai, Hong Kong, Singapore, Kelang, Laem Chabang, Colombo, Dubai, Barcelona, Antwerp, and Hamburg. We develop an improved, inseparable data envelopment analysis (DEA) model with slack-based measures (SBMs) to evaluate and compare the environmental performance and operational efficiency, and we incorporate the desirable output of container throughput as well as the undesirable output of CO₂ emission. Our results show that. Overall. these container ports perform better in terms of operational efficiency than environmental performance. We also provide insights for management and policy makers for container ports with different levels of operational efficiency and environmental performance.