A magnesium-based metal-organic framework (Mg-MOF-74) exhibits excellent CO₂ adsorption under ambient conditions. However, the photostability of Mg-MOF-74 for CO₂ adsorption is poor. In this study, Mg _x Cu_1-x -MOF-74 was synthesized by using a facile "one-pot" method. Furthermore, the effects of synthesis conditions on the CO₂ adsorption capacity were investigated comprehensively. X-ray diffraction, Fourier transform infrared, scanning electron microscopy, thermo gravimetric analysis, inductively coupled plasma atomic emission spectroscopy, ultraviolet-visible spectroscopy and photoluminescence spectroscopy, and CO₂ static adsorption-desorption techniques were used to characterize the structures, morphology, and physicochemical properties of Mg _x Cu_1-x -MOF-74. CO₂ uptake of Mg _x Cu_1-x -MOF-74 under visible light illumination was measured by the CO₂ static adsorption test combined with the Xe lamp. The results revealed that Mg _x Cu_1-x -MOF-74 exhibited excellent photocatalytic activity. Furthermore, the CO₂ adsorption capacity of Mg _x Cu_1-x -MOF-74 was excellent at a synthesis temperature and time of 398 K and 24 h in dimethylformamide (DMF)-EtOH-MeOH mixing solvents, respectively. Mg _x Cu_1-x -MOF-74 retained a crystal structure similar to that of the corresponding monometallic MOF-74, and its CO₂ uptake under visible light was superior to that of the corresponding monometallic MOF-74. Particularly, the CO₂ uptake of Mg_0.4Cu_0.6-MOF-74 under Xe lamp illumination for 24 h was the highest, up to 3.52 mmol·g^-1, which was 1.18 and 2.09 times higher than that of Mg- and Cu-MOF-74, respectively. The yield of the photocatalytic reduction of CO₂ to CO was 49.44 μmol·g_cat ^-1 over Mg_0.4Cu_0.6-MOF-74 under visible light for 8 h. Mg²⁺ and Cu²⁺ functioned as open alkali metal that could adsorb and activate CO₂. The synergistic effect between Mg and Cu metal strengthened Mg _x Cu_1-x -MOF-74 photostability for CO₂ adsorption and broadened the scope of its photocatalytic application. The "bimetallic" strategy exhibits considerable potential for use in MOF-based semiconductor composites and provides a feasible method for catalyst design with remarkable CO₂ adsorption capacity and photocatalytic activity.

Based on the ligand H₄Salen-8^tBu (salen-4), a new dinuclear cobalt complex (salen-4)[Co(III)TFA]₂ (salen-4 = 3,5-di-tert-butylsalicylaldehyde-3,3′-diaminobiphenylamine; TFA = trifluoroacetic acid) has been firstly synthesized and characterized. It shows high catalytic activity for the copolymerization of propylene oxide (PO) and carbon dioxide (CO₂), yielding regioregular poly(propylene carbonate) (PPC) with little generation of propylene carbonate (PC) by-product. It has been found that (salen-4)[Co(III)TFA]₂ shows higher activity at milder conditions, generating a polymer with maximum Mn of 293 kg/mol and a narrow molecular weight distribution PDI of 1.35. The influences of reaction time, CO₂ pressure, reaction temperature, nature of the cocatalyst, catalyst dosage and substrate concentration on the molecular weight, yield and selectivity of the polymer were explored in detail. The results showed that the (salen-4)[Co(III)TFA]₂/[PPN]TFA catalyst system demonstrated a remarkable TOF as high as 735 h^–1. In addition, a hypothetical catalytic reaction mechanism was proposed based on density functional theory (DFT) calculations and the catalytic reaction results of the (salen-4)[Co(III)TFA]₂.

Two pentacobalt(II) EMACs were synthesized. A pyrazine-modulated tripyridyldiamine resulted in an EMAC with fully delocalized Co–Co bonds along molecules. From a pyrazine- and naphthyridine-containing ligand, a defective cobalt linear EMAC with an 8-coordinated cobalt(II) in the center was obtained for the first time. An electrochemistry study on the defective pentacobalt chain compound showed redox peaks at E_1/2 = −1.00, +0.76, and +0.98 V (versus E_Ag/AgCl), indicating that it is quite stable and very resistant to both oxidation and reduction. Research on magnetism revealed that the fully delocalized Co EMAC is a spin mixture, and the defective cobalt EMAC showed a high-spin mononuclear cobalt(II) behaviour with a magnetic moment of 2.63μ_B per molecule at room temperature. Measurement on molecular electric conductance by STM bj showed a single-molecular resistance of 15.4 (±3.1) MΩ for defective and 12.3 (±2.6) MΩ for delocalized pentacobalt complexes.

New pentachromoium metal string complexes [Cr₅(μ₅-L)₄X₂] (X = Cl⁻, L = dppzda^{2 −} (1), dpzpda^{2 −} (2); X = NCS⁻, L = dppzda^{2 −} (3), dpzpda^{2 −} (4)) were designed and synthesized through pyrazine-modulation of tripyridyldiamine ligand. X-Ray crystallographic studies revealed a linear metal chain structure consisting of two quadruple Cr–Cr bonds and a separated high spin Cr(II) at an end in crystallized form. A quintet ground state was observed for all pentachromium(II) molecules by magnetic study with g values of 2.04–2.18. While the electronic structure remained unchanged after the modification of ligands, electrochemistry showed a significant change in the molecular orbital energy levels of metal string molecules. Observation of the first oxidation peak of 1 at +0.57 V and of 2 at +0.73 V revealed that these complexes are quite resistant to oxidation. Single molecular conductance measurements showed that the complex exhibited good electronic conductance.

In this study, a high-activity Zn–Co double metal cyanide complex was synthesized and used to catalyze the ternary polymerization of carbon dioxide, propylene oxide, and itaconic anhydride to produce a new class of polypropylene carbonates characterized by excellent performance and low ether content. The number average molecular weight of the terpolymer was as high as 2.14 × 10 ⁵ g·mol ⁻¹ , and the polydispersity index was as high as 1.58. In the case of PPCIAn ₃ , the 5% weight loss temperature increased by 70°C, the total weight loss temperature increased by 100°C, the tensile strength increased by 6.6 MPa, and the elongation at break decreased to 14.5% with respect to traditional polypropylene carbonate. The apparent efficiency of the catalyst was as high as 45.79 g _polymer /g _catalyst , indicating its high catalytic activity. ¹ H-NMR spectrometry, gel permeation chromatography, differential scanning calorimetry, thermogravimetric analysis, and in situ Fourier-transform infrared spectroscopy were used to characterize the polymerization process and the structural properties of the obtained terpolymers.